{"id":448,"date":"2018-08-24T15:03:25","date_gmt":"2018-08-24T19:03:25","guid":{"rendered":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/chapter\/10-6-metamorphic-hydrothermal-processes-and-metasomatism-2\/"},"modified":"2021-10-05T12:21:55","modified_gmt":"2021-10-05T16:21:55","slug":"10-6-metamorphic-hydrothermal-processes-and-metasomatism-2","status":"publish","type":"chapter","link":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/chapter\/10-6-metamorphic-hydrothermal-processes-and-metasomatism-2\/","title":{"raw":"10.6 Metamorphic Hydrothermal Processes and Metasomatism","rendered":"10.6 Metamorphic Hydrothermal Processes and Metasomatism"},"content":{"raw":"The heat from a body of magma in the upper crust can create a very dynamic situation with geologically interesting and economically important implications. In the simplest cases, water does not play a big role, and the main process is heat transfer from the pluton to the surrounding rock, creating a zone of contact metamorphism (Figure 10.39a). In many cases, however, water is released from the magma body as crystallization takes place, and this water is dispersed along fractures in the surrounding rock (Figure 10.39b).\r\n\r\n&nbsp;\r\n\r\n[caption id=\"attachment_346\" align=\"aligncenter\" width=\"652\"]<a href=\"https:\/\/openpress.usask.ca\/app\/uploads\/sites\/29\/2017\/05\/metamorphism-and-alteration-around-a-pluton.png\"><img class=\" wp-image-444\" src=\"https:\/\/pressbooks.bccampus.ca\/knowinghome\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-1024x350.png\" alt=\"\" width=\"652\" height=\"223\" \/><\/a> <strong>Figure 10.39<\/strong> Metamorphism and alteration around a pluton in the upper crust. (a) Thermal metamorphism only (within the purple zone); (b) Thermal metamorphism plus veining (white) related to dispersal of magmatic fluids into the overlying rock; (c) Thermal metamorphism plus veining from magmatic fluids plus alteration and possible formation of metallic minerals (hatched yellow areas) from convection of groundwater. Source: Steven Earle (2015), CC BY 4.0. <a href=\"http:\/\/opentextbc.ca\/geology\/wp-content\/uploads\/sites\/110\/2015\/07\/metamorphism-and-alteration-around-a-pluton.png\" rel=\"noopener\">View source.<\/a>[\/caption]\r\n\r\nThe water released from a magma chamber is typically rich in dissolved minerals. As this water cools, it interacts with the surrounding rocks, changing both the chemistry of the water and the chemistry of the rocks. This can cause minerals to precipitate from the water. Minerals can also precipitate if the water boils because of a drop in pressure.\r\n\r\nPrecipitated minerals form veins within fractures in the surrounding rock. Quartz veins are commonly formed in this situation, and can contain other minerals such as pyrite, hematite, calcite, and even silver and gold.\r\n\r\nHeat from the magma body will cause surrounding groundwater to expand and then rise toward the surface. In some cases, this may initiate a convection system where groundwater circulates past the pluton. Such a system could operate for thousands of years, resulting in the circulation of millions of tonnes of groundwater from the surrounding region past the pluton.\r\n\r\nHot water circulating through the rocks and interacting chemically with them can lead to significant changes in the mineralogy of the rock, including alteration of feldspars to clays, and deposition of quartz, calcite, and other minerals in fractures and other open spaces (Figure 10.40). Chemical change in rocks due to interaction with hot water is called <strong>hydrothermal alteration<\/strong>.\r\n\r\n&nbsp;\r\n\r\n[caption id=\"attachment_445\" align=\"aligncenter\" width=\"400\"]<a href=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2.jpg\"><img class=\"wp-image-445\" src=\"https:\/\/pressbooks.bccampus.ca\/knowinghome\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-1024x739.jpg\" alt=\"\" width=\"400\" height=\"289\" \/><\/a> <strong>Figure 10.40<\/strong> White veins of calcite in limestone of the Comox Formation, Nanaimo BC. Quarter for scale. Source: Steven Earle (2016), CC BY 4.0. <a href=\"https:\/\/opentextbc.ca\/physicalgeologyearle\/wp-content\/uploads\/sites\/145\/2016\/03\/calcite-vein-2.jpg\" rel=\"noopener\">View source.<\/a>[\/caption]\r\n<h1>Metasomatism<\/h1>\r\nMetamorphic reactions involve the release of fluids as minerals change, and chemical reactions with locally-derived fluids. However, if a large amount of externally-derived fluid\u2014such that supplied by magma\u2014is flushed through the system at the high pressures and temperatures characteristic of metamorphism, it can substantially alter the chemical composition of the rock. This type of hydrothermal alteration is called <strong>metasomatism<\/strong>.\r\n\r\nA special type of metasomatism takes place where a hot pluton intrudes into carbonate rock such as limestone. Magmatic fluids rich in silica, calcium, magnesium, iron, and other elements can dramatically change the chemistry of the limestone, forming minerals that would not normally exist in either the igneous rock or limestone. A rock called <strong>skarn<\/strong> results, containing minerals such as garnet, epidote, magnetite, and pyroxene, among others (Figure 10.41).\r\n\r\n[caption id=\"attachment_446\" align=\"aligncenter\" width=\"383\"]<a href=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037.jpg\"><img class=\"wp-image-446\" src=\"https:\/\/pressbooks.bccampus.ca\/knowinghome\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-1024x871.jpg\" alt=\"\" width=\"383\" height=\"326\" \/><\/a> <strong>Figure 10.41<\/strong> Skarn from Mount Monzoni, Northern Italy, with recrystallized calcite (blue), garnet (brown), and pyroxene (green). The rock is 6 cm across. Source: Siim Sepp (2012), CC BY-SA 3.0. <a href=\"https:\/\/commons.wikimedia.org\/wiki\/File:00031_6_cm_grossular_calcite_augite_skarn.jpg\" rel=\"noopener\">View source.<\/a>[\/caption]\r\n\r\n<div class=\"textbox shaded\">\r\n\r\n<strong>Concept Check<\/strong>\r\n\r\n[h5p id=\"68\"]\r\n\r\n&nbsp;\r\n\r\n<strong><a id=\"225\"><\/a>Practice with Contact Metamorphism and Metasomatism<\/strong>\r\n\r\n[h5p id=\"225\"]\r\n\r\n<\/div>","rendered":"<p>The heat from a body of magma in the upper crust can create a very dynamic situation with geologically interesting and economically important implications. In the simplest cases, water does not play a big role, and the main process is heat transfer from the pluton to the surrounding rock, creating a zone of contact metamorphism (Figure 10.39a). In many cases, however, water is released from the magma body as crystallization takes place, and this water is dispersed along fractures in the surrounding rock (Figure 10.39b).<\/p>\n<p>&nbsp;<\/p>\n<figure id=\"attachment_346\" aria-describedby=\"caption-attachment-346\" style=\"width: 652px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/openpress.usask.ca\/app\/uploads\/sites\/29\/2017\/05\/metamorphism-and-alteration-around-a-pluton.png\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-444\" src=\"https:\/\/pressbooks.bccampus.ca\/knowinghome\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-1024x350.png\" alt=\"\" width=\"652\" height=\"223\" srcset=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-1024x350.png 1024w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-300x103.png 300w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-768x263.png 768w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-1536x525.png 1536w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-65x22.png 65w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-225x77.png 225w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton-350x120.png 350w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2018\/08\/metamorphism-and-alteration-around-a-pluton.png 1960w\" sizes=\"auto, (max-width: 652px) 100vw, 652px\" \/><\/a><figcaption id=\"caption-attachment-346\" class=\"wp-caption-text\"><strong>Figure 10.39<\/strong> Metamorphism and alteration around a pluton in the upper crust. (a) Thermal metamorphism only (within the purple zone); (b) Thermal metamorphism plus veining (white) related to dispersal of magmatic fluids into the overlying rock; (c) Thermal metamorphism plus veining from magmatic fluids plus alteration and possible formation of metallic minerals (hatched yellow areas) from convection of groundwater. Source: Steven Earle (2015), CC BY 4.0. <a href=\"http:\/\/opentextbc.ca\/geology\/wp-content\/uploads\/sites\/110\/2015\/07\/metamorphism-and-alteration-around-a-pluton.png\" rel=\"noopener\">View source.<\/a><\/figcaption><\/figure>\n<p>The water released from a magma chamber is typically rich in dissolved minerals. As this water cools, it interacts with the surrounding rocks, changing both the chemistry of the water and the chemistry of the rocks. This can cause minerals to precipitate from the water. Minerals can also precipitate if the water boils because of a drop in pressure.<\/p>\n<p>Precipitated minerals form veins within fractures in the surrounding rock. Quartz veins are commonly formed in this situation, and can contain other minerals such as pyrite, hematite, calcite, and even silver and gold.<\/p>\n<p>Heat from the magma body will cause surrounding groundwater to expand and then rise toward the surface. In some cases, this may initiate a convection system where groundwater circulates past the pluton. Such a system could operate for thousands of years, resulting in the circulation of millions of tonnes of groundwater from the surrounding region past the pluton.<\/p>\n<p>Hot water circulating through the rocks and interacting chemically with them can lead to significant changes in the mineralogy of the rock, including alteration of feldspars to clays, and deposition of quartz, calcite, and other minerals in fractures and other open spaces (Figure 10.40). Chemical change in rocks due to interaction with hot water is called <strong>hydrothermal alteration<\/strong>.<\/p>\n<p>&nbsp;<\/p>\n<figure id=\"attachment_445\" aria-describedby=\"caption-attachment-445\" style=\"width: 400px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-445\" src=\"https:\/\/pressbooks.bccampus.ca\/knowinghome\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-1024x739.jpg\" alt=\"\" width=\"400\" height=\"289\" srcset=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-1024x739.jpg 1024w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-300x217.jpg 300w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-768x554.jpg 768w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-65x47.jpg 65w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-225x162.jpg 225w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2-350x253.jpg 350w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/calcite-vein-2.jpg 1139w\" sizes=\"auto, (max-width: 400px) 100vw, 400px\" \/><\/a><figcaption id=\"caption-attachment-445\" class=\"wp-caption-text\"><strong>Figure 10.40<\/strong> White veins of calcite in limestone of the Comox Formation, Nanaimo BC. Quarter for scale. Source: Steven Earle (2016), CC BY 4.0. <a href=\"https:\/\/opentextbc.ca\/physicalgeologyearle\/wp-content\/uploads\/sites\/145\/2016\/03\/calcite-vein-2.jpg\" rel=\"noopener\">View source.<\/a><\/figcaption><\/figure>\n<h1>Metasomatism<\/h1>\n<p>Metamorphic reactions involve the release of fluids as minerals change, and chemical reactions with locally-derived fluids. However, if a large amount of externally-derived fluid\u2014such that supplied by magma\u2014is flushed through the system at the high pressures and temperatures characteristic of metamorphism, it can substantially alter the chemical composition of the rock. This type of hydrothermal alteration is called <strong>metasomatism<\/strong>.<\/p>\n<p>A special type of metasomatism takes place where a hot pluton intrudes into carbonate rock such as limestone. Magmatic fluids rich in silica, calcium, magnesium, iron, and other elements can dramatically change the chemistry of the limestone, forming minerals that would not normally exist in either the igneous rock or limestone. A rock called <strong>skarn<\/strong> results, containing minerals such as garnet, epidote, magnetite, and pyroxene, among others (Figure 10.41).<\/p>\n<figure id=\"attachment_446\" aria-describedby=\"caption-attachment-446\" style=\"width: 383px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-446\" src=\"https:\/\/pressbooks.bccampus.ca\/knowinghome\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-1024x871.jpg\" alt=\"\" width=\"383\" height=\"326\" srcset=\"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-1024x871.jpg 1024w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-300x255.jpg 300w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-768x653.jpg 768w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-65x55.jpg 65w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-225x191.jpg 225w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037-350x298.jpg 350w, https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-content\/uploads\/sites\/1304\/2021\/03\/image037.jpg 1204w\" sizes=\"auto, (max-width: 383px) 100vw, 383px\" \/><\/a><figcaption id=\"caption-attachment-446\" class=\"wp-caption-text\"><strong>Figure 10.41<\/strong> Skarn from Mount Monzoni, Northern Italy, with recrystallized calcite (blue), garnet (brown), and pyroxene (green). The rock is 6 cm across. Source: Siim Sepp (2012), CC BY-SA 3.0. <a href=\"https:\/\/commons.wikimedia.org\/wiki\/File:00031_6_cm_grossular_calcite_augite_skarn.jpg\" rel=\"noopener\">View source.<\/a><\/figcaption><\/figure>\n<div class=\"textbox shaded\">\n<p><strong>Concept Check<\/strong><\/p>\n<div id=\"h5p-68\">\n<div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-68\" class=\"h5p-iframe\" data-content-id=\"68\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"Difference between metamorphism and metasomatism\"><\/iframe><\/div>\n<\/div>\n<p>&nbsp;<\/p>\n<p><strong><a id=\"225\"><\/a>Practice with Contact Metamorphism and Metasomatism<\/strong><\/p>\n<div id=\"h5p-225\">\n<div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-225\" class=\"h5p-iframe\" data-content-id=\"225\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"Contact metamorphic rocks and hydrothermal alteration\"><\/iframe><\/div>\n<\/div>\n<\/div>\n","protected":false},"author":103,"menu_order":6,"template":"","meta":{"pb_show_title":"on","pb_short_title":"","pb_subtitle":"","pb_authors":[],"pb_section_license":""},"chapter-type":[],"contributor":[],"license":[],"class_list":["post-448","chapter","type-chapter","status-publish","hentry"],"part":394,"_links":{"self":[{"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/chapters\/448","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/chapters"}],"about":[{"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/wp\/v2\/types\/chapter"}],"author":[{"embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/wp\/v2\/users\/103"}],"version-history":[{"count":7,"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/chapters\/448\/revisions"}],"predecessor-version":[{"id":2608,"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/chapters\/448\/revisions\/2608"}],"part":[{"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/parts\/394"}],"metadata":[{"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/chapters\/448\/metadata\/"}],"wp:attachment":[{"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/wp\/v2\/media?parent=448"}],"wp:term":[{"taxonomy":"chapter-type","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/pressbooks\/v2\/chapter-type?post=448"},{"taxonomy":"contributor","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/wp\/v2\/contributor?post=448"},{"taxonomy":"license","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/physicalgeologyh5p\/wp-json\/wp\/v2\/license?post=448"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}