{"id":505,"date":"2021-05-30T01:20:31","date_gmt":"2021-05-30T05:20:31","guid":{"rendered":"https:\/\/pressbooks.bccampus.ca\/thermo1\/chapter\/what-is-thermodynamics-about\/"},"modified":"2022-08-02T17:57:57","modified_gmt":"2022-08-02T21:57:57","slug":"what-is-thermodynamics-about","status":"publish","type":"chapter","link":"https:\/\/pressbooks.bccampus.ca\/thermo1\/chapter\/what-is-thermodynamics-about\/","title":{"raw":"1.1 What is thermodynamics about?","rendered":"1.1 What is thermodynamics about?"},"content":{"raw":"<div class=\"what-is-thermodynamics-about?\">\r\n<p class=\"import-Normal\" style=\"text-align: justify\">You probably have this experience; when you rub your hands quickly for a few minutes, your hands will start to feel warmer. How is this common phenomenon related to thermodynamics? Well, when you rub your hands quickly, your muscles do [pb_glossary id=\"721\"]work[\/pb_glossary]. This work is then converted to [pb_glossary id=\"722\"]heat[\/pb_glossary]; therefore, you feel warmer.\u00a0 Heat and work are two forms of energy. Work can be converted to heat, as seen in this daily example. However, can heat be converted to work? Can we use heat to produce work?<\/p>\r\n&nbsp;\r\n<p class=\"import-Normal\" style=\"text-align: justify\">[pb_glossary id=\"556\"]Heat engine[\/pb_glossary] is a device that produces work continuously by absorbing heat from a high-temperature heat source and rejecting the waste heat to a low-temperature heat sink. Since the 17<sup>th<\/sup> century, various heat engines were invented in an attempt to harness work from heat. <a href=\"#watt\">Figure 1.1.1<\/a> illustrates Watt\u2019s engine invented by Scottish engineer James Watt in the late 18<sup>th<\/sup> century. Watt\u2019s engine is <span lang=\"en-US\" xml:lang=\"en-US\">one of the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">most <\/span><span lang=\"en-US\" xml:lang=\"en-US\">successful <\/span><span lang=\"en-US\" xml:lang=\"en-US\">early heat engine<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. Its <\/span>main components <span lang=\"en-US\" xml:lang=\"en-US\">are a boiler (not shown in the figure) and a condenser, each connecting to a piston-cylinder device. The two valves, <em>V<\/em> and <em>V<\/em><em lang=\"en-US\" xml:lang=\"en-US\">\u2019<\/em>, control the flow of steam into and out of the cylinder. <\/span><span lang=\"en-US\" xml:lang=\"en-US\">When valve <\/span><em>V<\/em><span lang=\"en-US\" xml:lang=\"en-US\"> opens, valve <\/span><em>V<\/em><em lang=\"en-US\" xml:lang=\"en-US\">\u2019<\/em><span lang=\"en-US\" xml:lang=\"en-US\"> remains closed. S<\/span><span lang=\"en-US\" xml:lang=\"en-US\">team <\/span><span lang=\"en-US\" xml:lang=\"en-US\">from<\/span> <span lang=\"en-US\" xml:lang=\"en-US\">the<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> boiler enters the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">cylinder, pushing the piston up until it reaches the top of the cylinder. <\/span><span lang=\"en-US\" xml:lang=\"en-US\">Then valve <\/span><em lang=\"en-US\" xml:lang=\"en-US\">V<\/em><em lang=\"en-US\" xml:lang=\"en-US\">\u2019<\/em> <span lang=\"en-US\" xml:lang=\"en-US\">open<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">,<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> and valve <\/span><em lang=\"en-US\" xml:lang=\"en-US\">V<\/em> <span lang=\"en-US\" xml:lang=\"en-US\">close<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. The <\/span>s<span lang=\"en-US\" xml:lang=\"en-US\">team <\/span><span lang=\"en-US\" xml:lang=\"en-US\">in the cylinder escapes to the condenser and is <\/span><span lang=\"en-US\" xml:lang=\"en-US\">condensed<\/span><span lang=\"en-US\" xml:lang=\"en-US\">, <\/span><span lang=\"en-US\" xml:lang=\"en-US\">creating <\/span><span lang=\"en-US\" xml:lang=\"en-US\">a <\/span><span lang=\"en-US\" xml:lang=\"en-US\">vacuum in the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">cylinder. Consequently, the piston move<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> downward under <\/span><span lang=\"en-US\" xml:lang=\"en-US\">atmospheric pressure<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. <\/span><span lang=\"en-US\" xml:lang=\"en-US\">The reciprocating motion of the piston drives the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">pivoting <\/span><span lang=\"en-US\" xml:lang=\"en-US\">beam <\/span><em lang=\"en-US\" xml:lang=\"en-US\">DEF<\/em><span lang=\"en-US\" xml:lang=\"en-US\">, which then powers <\/span><span lang=\"en-US\" xml:lang=\"en-US\">the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">pump <\/span><span lang=\"en-US\" xml:lang=\"en-US\">chained to the beam. Watt's engine demonstrates how heat is converted to work. This conversion relies on the phase change of a working fluid, e.g., water, in the Watt's engine. The boiler in the Watt's engine is the heat source, where the hot steam is generated; and the condenser is the heat sink, where the hot steam is cooled and condensed to liquid water. All heat engines need a working fluid circulating in a specially-arranged set of equipment, which operates between a high-temperature heat source and a low-temperature heat sink. <\/span><span lang=\"en-US\" xml:lang=\"en-US\"><a href=\"#HE_schematic\">Figure 1.1.2<\/a> is a schematic drawing of a heat engine. <a id=\"watt\"><\/a> The yellow circle represents the heat engine consisting of a set of equipment.\r\n<\/span><\/p>\r\n&nbsp;\r\n\r\n<\/div>\r\n<div class=\"what-is-thermodynamics-about?\">\r\n\r\n&nbsp;\r\n\r\n[caption id=\"attachment_756\" align=\"aligncenter\" width=\"255\"]<a href=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783.png\" target=\"_blank\" rel=\"noopener\"><img class=\"wp-image-756\" src=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-233x300.png\" alt=\"James Watt's heat engine\" width=\"255\" height=\"328\" \/><\/a> <strong>Figure 1.1.1<\/strong> <a id=\"HE_schematic\"><\/a> <em>Watt's heat engine<\/em>[\/caption]\r\n\r\n&nbsp;\r\n\r\n[caption id=\"attachment_444\" align=\"aligncenter\" width=\"300\"]<a href=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine.png\" target=\"_blank\" rel=\"noopener\"><img class=\"wp-image-444 size-medium\" src=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine-300x300.png\" alt=\"A schematic drawing of heat engine generating power by absorbing heat from a hot source\" width=\"300\" height=\"300\" \/><\/a> <strong>Figure 1.1.2<\/strong> <em>Schematic drawing of a heat engine<\/em>[\/caption]\r\n<p class=\"import-Normal\" style=\"text-align: justify\">By examining <a href=\"#HE_schematic\">Figure 1.1.2<\/a>, you might notice that a certain amount of heat is not converted to work. It is true that <strong><em>not<\/em><em> all<\/em><em> of the <\/em><em>heat from a heat source\u00a0<\/em><\/strong><strong><em>can be converted to useful work<\/em><em>!\u00a0<\/em><\/strong> Heat engines and their underlying principles are governed by the two fundamental laws of thermodynamics, the first and second laws of thermodynamics. We will briefly introduce the two laws here and will provide detailed explanations in Chapters 4-6.<\/p>\r\n\r\n<ul style=\"text-align: justify\">\r\n \t<li><strong>The first law of <\/strong><strong>thermodynamic<\/strong><strong>s<\/strong> is about <span lang=\"en-US\" xml:lang=\"en-US\">energy<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> conserv<\/span><span lang=\"en-US\" xml:lang=\"en-US\">ation. <\/span> <span lang=\"en-US\" xml:lang=\"en-US\">Energy<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> can neither be created nor destroyed. It can only <\/span><span lang=\"en-US\" xml:lang=\"en-US\">be converted between different<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> forms.<\/span><\/li>\r\n \t<li><strong>The second law of thermodynamics<\/strong> explains <span lang=\"en-US\" xml:lang=\"en-US\">why all real processes are irreversible, and how the irreversibility of a process is quantified with the concept of entropy generation. In reality, all<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> processes<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> always occur in the direction of <\/span><span lang=\"en-US\" xml:lang=\"en-US\">producing positive entropy generation <\/span><span lang=\"en-US\" xml:lang=\"en-US\">due to the existence of <\/span><span lang=\"en-US\" xml:lang=\"en-US\">irreversibilities<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. From t<\/span><span lang=\"en-US\" xml:lang=\"en-US\">he s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">econd law<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> of thermodynamics, we can estimate the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">theoretical limit of <\/span><span lang=\"en-US\" xml:lang=\"en-US\">efficiency that <\/span><span lang=\"en-US\" xml:lang=\"en-US\">a real thermodynamic process or system can possibly achieve<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. <\/span><\/li>\r\n<\/ul>\r\n<p class=\"import-Normal\" style=\"text-align: justify\">[pb_glossary id=\"561\"]<strong>T<\/strong><strong>hermodynamics<\/strong>[\/pb_glossary] emerged in the early 19<sup>th<\/sup> century with the inventions of heat engines. It originally focused on the scientific theories of heat-work conversion, and the operations and efficiency improvement of heat engines. Nowadays, the applications of thermodynamics have extended to all fields related to energy conversion and conservation. In engineering fields, the principles of thermodynamics are widely used in the design of thermal systems, such as power plants using different energy sources (e.g., steam, gas, nuclear, hydro, wind, and solar), air conditioning and refrigeration systems, jet engines, biomedical devices, and chemical processes, to name but a few. <a href=\"#power_plant\">Figure 1.1.3<\/a> is a schematic drawing of a nuclear power plant, <a id=\"power_plant\"><\/a> whose performance and efficiency are governed by the fundamental principles of thermodynamics.<\/p>\r\n\r\n<\/div>\r\n\r\n[caption id=\"attachment_760\" align=\"aligncenter\" width=\"744\"]<a href=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_.png\" target=\"_blank\" rel=\"noopener\"><img class=\"wp-image-760 size-full\" src=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_.png\" alt=\"A nuclear power plant consisting of reactor building, turbine building and cooling tower\" width=\"744\" height=\"500\" \/><\/a> <strong>Figure 1.1.3<\/strong> <em>Nuclear Power Plant<\/em>[\/caption]\r\n\r\n<div class=\"textbox textbox--exercises\"><header class=\"textbox__header\">\r\n<p class=\"textbox__title\">Practice Problems<\/p>\r\n\r\n<\/header>\r\n<div class=\"textbox__content\">\r\n\r\n[h5p id=\"25\"]\r\n\r\n&nbsp;\r\n\r\n<\/div>\r\n<\/div>","rendered":"<div class=\"what-is-thermodynamics-about?\">\n<p class=\"import-Normal\" style=\"text-align: justify\">You probably have this experience; when you rub your hands quickly for a few minutes, your hands will start to feel warmer. How is this common phenomenon related to thermodynamics? Well, when you rub your hands quickly, your muscles do <a class=\"glossary-term\" aria-haspopup=\"dialog\" aria-describedby=\"definition\" href=\"#term_505_721\">work<\/a>. This work is then converted to <a class=\"glossary-term\" aria-haspopup=\"dialog\" aria-describedby=\"definition\" href=\"#term_505_722\">heat<\/a>; therefore, you feel warmer.\u00a0 Heat and work are two forms of energy. Work can be converted to heat, as seen in this daily example. However, can heat be converted to work? Can we use heat to produce work?<\/p>\n<p>&nbsp;<\/p>\n<p class=\"import-Normal\" style=\"text-align: justify\"><a class=\"glossary-term\" aria-haspopup=\"dialog\" aria-describedby=\"definition\" href=\"#term_505_556\">Heat engine<\/a> is a device that produces work continuously by absorbing heat from a high-temperature heat source and rejecting the waste heat to a low-temperature heat sink. Since the 17<sup>th<\/sup> century, various heat engines were invented in an attempt to harness work from heat. <a href=\"#watt\">Figure 1.1.1<\/a> illustrates Watt\u2019s engine invented by Scottish engineer James Watt in the late 18<sup>th<\/sup> century. Watt\u2019s engine is <span lang=\"en-US\" xml:lang=\"en-US\">one of the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">most <\/span><span lang=\"en-US\" xml:lang=\"en-US\">successful <\/span><span lang=\"en-US\" xml:lang=\"en-US\">early heat engine<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. Its <\/span>main components <span lang=\"en-US\" xml:lang=\"en-US\">are a boiler (not shown in the figure) and a condenser, each connecting to a piston-cylinder device. The two valves, <em>V<\/em> and <em>V<\/em><em lang=\"en-US\" xml:lang=\"en-US\">\u2019<\/em>, control the flow of steam into and out of the cylinder. <\/span><span lang=\"en-US\" xml:lang=\"en-US\">When valve <\/span><em>V<\/em><span lang=\"en-US\" xml:lang=\"en-US\"> opens, valve <\/span><em>V<\/em><em lang=\"en-US\" xml:lang=\"en-US\">\u2019<\/em><span lang=\"en-US\" xml:lang=\"en-US\"> remains closed. S<\/span><span lang=\"en-US\" xml:lang=\"en-US\">team <\/span><span lang=\"en-US\" xml:lang=\"en-US\">from<\/span> <span lang=\"en-US\" xml:lang=\"en-US\">the<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> boiler enters the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">cylinder, pushing the piston up until it reaches the top of the cylinder. <\/span><span lang=\"en-US\" xml:lang=\"en-US\">Then valve <\/span><em lang=\"en-US\" xml:lang=\"en-US\">V<\/em><em lang=\"en-US\" xml:lang=\"en-US\">\u2019<\/em> <span lang=\"en-US\" xml:lang=\"en-US\">open<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">,<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> and valve <\/span><em lang=\"en-US\" xml:lang=\"en-US\">V<\/em> <span lang=\"en-US\" xml:lang=\"en-US\">close<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. The <\/span>s<span lang=\"en-US\" xml:lang=\"en-US\">team <\/span><span lang=\"en-US\" xml:lang=\"en-US\">in the cylinder escapes to the condenser and is <\/span><span lang=\"en-US\" xml:lang=\"en-US\">condensed<\/span><span lang=\"en-US\" xml:lang=\"en-US\">, <\/span><span lang=\"en-US\" xml:lang=\"en-US\">creating <\/span><span lang=\"en-US\" xml:lang=\"en-US\">a <\/span><span lang=\"en-US\" xml:lang=\"en-US\">vacuum in the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">cylinder. Consequently, the piston move<\/span><span lang=\"en-US\" xml:lang=\"en-US\">s<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> downward under <\/span><span lang=\"en-US\" xml:lang=\"en-US\">atmospheric pressure<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. <\/span><span lang=\"en-US\" xml:lang=\"en-US\">The reciprocating motion of the piston drives the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">pivoting <\/span><span lang=\"en-US\" xml:lang=\"en-US\">beam <\/span><em lang=\"en-US\" xml:lang=\"en-US\">DEF<\/em><span lang=\"en-US\" xml:lang=\"en-US\">, which then powers <\/span><span lang=\"en-US\" xml:lang=\"en-US\">the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">pump <\/span><span lang=\"en-US\" xml:lang=\"en-US\">chained to the beam. Watt&#8217;s engine demonstrates how heat is converted to work. This conversion relies on the phase change of a working fluid, e.g., water, in the Watt&#8217;s engine. The boiler in the Watt&#8217;s engine is the heat source, where the hot steam is generated; and the condenser is the heat sink, where the hot steam is cooled and condensed to liquid water. All heat engines need a working fluid circulating in a specially-arranged set of equipment, which operates between a high-temperature heat source and a low-temperature heat sink. <\/span><span lang=\"en-US\" xml:lang=\"en-US\"><a href=\"#HE_schematic\">Figure 1.1.2<\/a> is a schematic drawing of a heat engine. <a id=\"watt\"><\/a> The yellow circle represents the heat engine consisting of a set of equipment.<br \/>\n<\/span><\/p>\n<p>&nbsp;<\/p>\n<\/div>\n<div class=\"what-is-thermodynamics-about?\">\n<p>&nbsp;<\/p>\n<figure id=\"attachment_756\" aria-describedby=\"caption-attachment-756\" style=\"width: 255px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783.png\" target=\"_blank\" rel=\"noopener\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-756\" src=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-233x300.png\" alt=\"James Watt's heat engine\" width=\"255\" height=\"328\" srcset=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-233x300.png 233w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-795x1024.png 795w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-768x990.png 768w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-65x84.png 65w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-225x290.png 225w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783-350x451.png 350w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Watt7783.png 950w\" sizes=\"auto, (max-width: 255px) 100vw, 255px\" \/><\/a><figcaption id=\"caption-attachment-756\" class=\"wp-caption-text\"><strong>Figure 1.1.1<\/strong> <a id=\"HE_schematic\"><\/a> <em>Watt&#8217;s heat engine<\/em><\/figcaption><\/figure>\n<p>&nbsp;<\/p>\n<figure id=\"attachment_444\" aria-describedby=\"caption-attachment-444\" style=\"width: 300px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine.png\" target=\"_blank\" rel=\"noopener\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-444 size-medium\" src=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine-300x300.png\" alt=\"A schematic drawing of heat engine generating power by absorbing heat from a hot source\" width=\"300\" height=\"300\" srcset=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine.png 300w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine-150x150.png 150w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine-65x65.png 65w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/05\/Fig.-1-1_Heat_engine-225x225.png 225w\" sizes=\"auto, (max-width: 300px) 100vw, 300px\" \/><\/a><figcaption id=\"caption-attachment-444\" class=\"wp-caption-text\"><strong>Figure 1.1.2<\/strong> <em>Schematic drawing of a heat engine<\/em><\/figcaption><\/figure>\n<p class=\"import-Normal\" style=\"text-align: justify\">By examining <a href=\"#HE_schematic\">Figure 1.1.2<\/a>, you might notice that a certain amount of heat is not converted to work. It is true that <strong><em>not<\/em><em> all<\/em><em> of the <\/em><em>heat from a heat source\u00a0<\/em><\/strong><strong><em>can be converted to useful work<\/em><em>!\u00a0<\/em><\/strong> Heat engines and their underlying principles are governed by the two fundamental laws of thermodynamics, the first and second laws of thermodynamics. We will briefly introduce the two laws here and will provide detailed explanations in Chapters 4-6.<\/p>\n<ul style=\"text-align: justify\">\n<li><strong>The first law of <\/strong><strong>thermodynamic<\/strong><strong>s<\/strong> is about <span lang=\"en-US\" xml:lang=\"en-US\">energy<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> conserv<\/span><span lang=\"en-US\" xml:lang=\"en-US\">ation. <\/span> <span lang=\"en-US\" xml:lang=\"en-US\">Energy<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> can neither be created nor destroyed. It can only <\/span><span lang=\"en-US\" xml:lang=\"en-US\">be converted between different<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> forms.<\/span><\/li>\n<li><strong>The second law of thermodynamics<\/strong> explains <span lang=\"en-US\" xml:lang=\"en-US\">why all real processes are irreversible, and how the irreversibility of a process is quantified with the concept of entropy generation. In reality, all<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> processes<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> always occur in the direction of <\/span><span lang=\"en-US\" xml:lang=\"en-US\">producing positive entropy generation <\/span><span lang=\"en-US\" xml:lang=\"en-US\">due to the existence of <\/span><span lang=\"en-US\" xml:lang=\"en-US\">irreversibilities<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. From t<\/span><span lang=\"en-US\" xml:lang=\"en-US\">he s<\/span><span lang=\"en-US\" xml:lang=\"en-US\">econd law<\/span><span lang=\"en-US\" xml:lang=\"en-US\"> of thermodynamics, we can estimate the <\/span><span lang=\"en-US\" xml:lang=\"en-US\">theoretical limit of <\/span><span lang=\"en-US\" xml:lang=\"en-US\">efficiency that <\/span><span lang=\"en-US\" xml:lang=\"en-US\">a real thermodynamic process or system can possibly achieve<\/span><span lang=\"en-US\" xml:lang=\"en-US\">. <\/span><\/li>\n<\/ul>\n<p class=\"import-Normal\" style=\"text-align: justify\"><a class=\"glossary-term\" aria-haspopup=\"dialog\" aria-describedby=\"definition\" href=\"#term_505_561\"><strong>T<\/strong><strong>hermodynamics<\/strong><\/a> emerged in the early 19<sup>th<\/sup> century with the inventions of heat engines. It originally focused on the scientific theories of heat-work conversion, and the operations and efficiency improvement of heat engines. Nowadays, the applications of thermodynamics have extended to all fields related to energy conversion and conservation. In engineering fields, the principles of thermodynamics are widely used in the design of thermal systems, such as power plants using different energy sources (e.g., steam, gas, nuclear, hydro, wind, and solar), air conditioning and refrigeration systems, jet engines, biomedical devices, and chemical processes, to name but a few. <a href=\"#power_plant\">Figure 1.1.3<\/a> is a schematic drawing of a nuclear power plant, <a id=\"power_plant\"><\/a> whose performance and efficiency are governed by the fundamental principles of thermodynamics.<\/p>\n<\/div>\n<figure id=\"attachment_760\" aria-describedby=\"caption-attachment-760\" style=\"width: 744px\" class=\"wp-caption aligncenter\"><a href=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_.png\" target=\"_blank\" rel=\"noopener\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-760 size-full\" src=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_.png\" alt=\"A nuclear power plant consisting of reactor building, turbine building and cooling tower\" width=\"744\" height=\"500\" srcset=\"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_.png 744w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_-300x202.png 300w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_-65x44.png 65w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_-225x151.png 225w, https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-content\/uploads\/sites\/499\/2021\/06\/Fig.1-3-744px-Tmi-2_schematicaux.svg_-350x235.png 350w\" sizes=\"auto, (max-width: 744px) 100vw, 744px\" \/><\/a><figcaption id=\"caption-attachment-760\" class=\"wp-caption-text\"><strong>Figure 1.1.3<\/strong> <em>Nuclear Power Plant<\/em><\/figcaption><\/figure>\n<div class=\"textbox textbox--exercises\">\n<header class=\"textbox__header\">\n<p class=\"textbox__title\">Practice Problems<\/p>\n<\/header>\n<div class=\"textbox__content\">\n<div id=\"h5p-25\">\n<div class=\"h5p-iframe-wrapper\"><iframe id=\"h5p-iframe-25\" class=\"h5p-iframe\" data-content-id=\"25\" style=\"height:1px\" src=\"about:blank\" frameBorder=\"0\" scrolling=\"no\" title=\"S_1.1_Q\"><\/iframe><\/div>\n<\/div>\n<p>&nbsp;<\/p>\n<\/div>\n<\/div>\n<div class=\"media-attributions clear\" prefix:cc=\"http:\/\/creativecommons.org\/ns#\" prefix:dc=\"http:\/\/purl.org\/dc\/terms\/\"><h2>Media Attributions<\/h2><ul><li about=\"https:\/\/commons.wikimedia.org\/wiki\/File:Watt7783.png\"><a rel=\"cc:attributionURL\" href=\"https:\/\/commons.wikimedia.org\/wiki\/File:Watt7783.png\" property=\"dc:title\">Watt&#8217;s Heat Engine<\/a>  &copy;  <a rel=\"dc:creator\" href=\"https:\/\/en.wikipedia.org\/wiki\/User:Caltrop\" property=\"cc:attributionName\">Caltrop<\/a>    is licensed under a  <a rel=\"license\" href=\"https:\/\/creativecommons.org\/publicdomain\/mark\/1.0\/\">Public Domain<\/a> license<\/li><li about=\"https:\/\/commons.wikimedia.org\/wiki\/File:Heat_engine_summary.png\"><a rel=\"cc:attributionURL\" href=\"https:\/\/commons.wikimedia.org\/wiki\/File:Heat_engine_summary.png\" property=\"dc:title\">Schematic drawing of a heat engine<\/a>  &copy;  Brundl15    is licensed under a  <a rel=\"license\" href=\"https:\/\/creativecommons.org\/licenses\/by-sa\/4.0\/\">CC BY-SA (Attribution ShareAlike)<\/a> license<\/li><li about=\"https:\/\/commons.wikimedia.org\/wiki\/File:Tmi-2_schematicaux.svg\"><a rel=\"cc:attributionURL\" href=\"https:\/\/commons.wikimedia.org\/wiki\/File:Tmi-2_schematicaux.svg\" property=\"dc:title\">Nuclear Power Plant<\/a>  &copy;  <a rel=\"dc:creator\" href=\"https:\/\/commons.wikimedia.org\/wiki\/User:Anynobody\" property=\"cc:attributionName\">Anynobody<\/a>    is licensed under a  <a rel=\"license\" href=\"https:\/\/creativecommons.org\/licenses\/by-sa\/4.0\/\">CC BY-SA (Attribution ShareAlike)<\/a> license<\/li><\/ul><\/div><div class=\"glossary\"><span class=\"screen-reader-text\" id=\"definition\">definition<\/span><template id=\"term_505_721\"><div class=\"glossary__definition\" role=\"dialog\" data-id=\"term_505_721\"><div tabindex=\"-1\"><p>Work is a form of energy that is transferred to or from a body by applying a force on that body along a displacement.<\/p>\n<\/div><button><span aria-hidden=\"true\">&times;<\/span><span class=\"screen-reader-text\">Close definition<\/span><\/button><\/div><\/template><template id=\"term_505_722\"><div class=\"glossary__definition\" role=\"dialog\" data-id=\"term_505_722\"><div tabindex=\"-1\"><p>Heat is a form of energy. Heat transfer will take place between two objects if they are at different temperatures.<\/p>\n<\/div><button><span aria-hidden=\"true\">&times;<\/span><span class=\"screen-reader-text\">Close definition<\/span><\/button><\/div><\/template><template id=\"term_505_556\"><div class=\"glossary__definition\" role=\"dialog\" data-id=\"term_505_556\"><div tabindex=\"-1\"><p>Heat engine is a device that produces work by absorbing heat from a high-temperature body (heat source) and rejecting the waste heat to a low-temperature body (heat sink).<\/p>\n<\/div><button><span aria-hidden=\"true\">&times;<\/span><span class=\"screen-reader-text\">Close definition<\/span><\/button><\/div><\/template><template id=\"term_505_561\"><div class=\"glossary__definition\" role=\"dialog\" data-id=\"term_505_561\"><div tabindex=\"-1\"><p>Thermodynamics is a branch of science. It originally focused on the scientific theories of heat-work conversion, and the operations and efficiency improvement of heat engines. Nowadays, the applications of thermodynamics have extended to all fields related to energy conversion and conservation.<\/p>\n<\/div><button><span aria-hidden=\"true\">&times;<\/span><span class=\"screen-reader-text\">Close definition<\/span><\/button><\/div><\/template><\/div>","protected":false},"author":175,"menu_order":2,"template":"","meta":{"pb_show_title":"on","pb_short_title":"What is thermodynamics?","pb_subtitle":"","pb_authors":[],"pb_section_license":""},"chapter-type":[47],"contributor":[57],"license":[],"class_list":["post-505","chapter","type-chapter","status-publish","hentry","chapter-type-standard","contributor-claire-yan"],"part":251,"_links":{"self":[{"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/chapters\/505","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/chapters"}],"about":[{"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/wp\/v2\/types\/chapter"}],"author":[{"embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/wp\/v2\/users\/175"}],"version-history":[{"count":25,"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/chapters\/505\/revisions"}],"predecessor-version":[{"id":3946,"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/chapters\/505\/revisions\/3946"}],"part":[{"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/parts\/251"}],"metadata":[{"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/chapters\/505\/metadata\/"}],"wp:attachment":[{"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/wp\/v2\/media?parent=505"}],"wp:term":[{"taxonomy":"chapter-type","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/pressbooks\/v2\/chapter-type?post=505"},{"taxonomy":"contributor","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/wp\/v2\/contributor?post=505"},{"taxonomy":"license","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/thermo1\/wp-json\/wp\/v2\/license?post=505"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}