{"id":1661,"date":"2017-10-27T16:32:38","date_gmt":"2017-10-27T16:32:38","guid":{"rendered":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/chapter\/the-pauli-exclusion-principle\/"},"modified":"2017-11-08T03:27:46","modified_gmt":"2017-11-08T03:27:46","slug":"the-pauli-exclusion-principle","status":"publish","type":"chapter","link":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/chapter\/the-pauli-exclusion-principle\/","title":{"raw":"The Pauli Exclusion Principle","rendered":"The Pauli Exclusion Principle"},"content":{"raw":"\n<div class=\"textbox learning-objectives\">\n<h3 itemprop=\"educationalUse\">Learning Objectives<\/h3>\n<ul>\n<li>Define the composition of an atom along with its electrons, neutrons, and protons.<\/li>\n<li>Explain the Pauli exclusion principle and its application to the atom.<\/li>\n<li>Specify the shell and subshell symbols and their positions.<\/li>\n<li>Define the position of electrons in different shells of an atom.<\/li>\n<li>State the position of each element in the periodic table according to shell filling.<\/li>\n<\/ul>\n<\/div>\n<div class=\"bc-section section\" data-depth=\"1\" id=\"fs-id3018172\">\n<h1 data-type=\"title\">Multiple-Electron Atoms<\/h1>\n<p id=\"import-auto-id1487054\">All atoms except hydrogen are multiple-electron atoms. The physical and chemical properties of elements are directly related to the number of electrons a neutral atom has. The periodic table of the elements groups elements with similar properties into columns. This systematic organization is related to the number of electrons in a neutral atom, called the <span data-type=\"term\" id=\"import-auto-id1430981\">atomic number<\/span>, [latex]Z[\/latex]. We shall see in this section that the exclusion principle is key to the underlying explanations, and that it applies far beyond the realm of atomic physics.<\/p>\n<p id=\"import-auto-id3357761\">In 1925, the Austrian physicist Wolfgang Pauli (see <a href=\"#fs-id2688367\" class=\"autogenerated-content\">(Figure)<\/a>) proposed the following rule: No two electrons can have the same set of quantum numbers. That is, no two electrons can be in the same state. This statement is known as the <span data-type=\"term\" id=\"import-auto-id1931568\">Pauli exclusion principle<\/span>, because it excludes electrons from being in the same state. The Pauli exclusion principle is extremely powerful and very broadly applicable. It applies to any identical particles with half-integral intrinsic spin\u2014that is, having [latex]s=1\/2, 3\/2, ...[\/latex] Thus no two electrons can have the same set of quantum numbers.<\/p>\n<div data-type=\"note\" class=\"note\" data-has-label=\"true\" id=\"fs-id2440737\" data-label=\"\">\n<div data-type=\"title\" class=\"title\">Pauli Exclusion Principle<\/div>\n<p id=\"import-auto-id2024782\">No two electrons can have the same set of quantum numbers. That is, no two electrons can be in the same state.<\/p>\n<\/div>\n<div class=\"bc-figure figure\" id=\"fs-id2688367\">\n<div class=\"bc-figcaption figcaption\">The Austrian physicist Wolfgang Pauli (1900\u20131958) played a major role in the development of quantum mechanics. He proposed the exclusion principle; hypothesized the existence of an important particle, called the neutrino, before it was directly observed; made fundamental contributions to several areas of theoretical physics; and influenced many students who went on to do important work of their own. (credit: Nobel Foundation, via Wikimedia Commons)<\/div>\n<p><span data-type=\"media\" id=\"fs-id3177781\" data-alt=\"A black and white portrait of Austrian physicist Wolfgang Pauli.\"><img src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_01a.jpg\" data-media-type=\"image\/jpg\" alt=\"A black and white portrait of Austrian physicist Wolfgang Pauli.\" width=\"210\"><\/span><\/p><\/div>\n<p id=\"import-auto-id3105452\">Let us examine how the exclusion principle applies to electrons in atoms. The quantum numbers involved were defined in <a href=\"\/contents\/c1f0576f-1366-45d2-8f18-a54b8b35c1c5@10\">Quantum Numbers and Rules<\/a> as [latex]\\mathrm{n, l,}\\phantom{\\rule{0.25em}{0ex}}{m}_{l}\\mathrm{, s}[\/latex], and [latex]{m}_{s}[\/latex]. Since [latex]s[\/latex] is always [latex]1\/2[\/latex] for electrons, it is redundant to list [latex]s[\/latex], and so we omit it and specify the state of an electron by a set of four numbers [latex]\\left(n,\\phantom{\\rule{0.25em}{0ex}}l,\\phantom{\\rule{0.25em}{0ex}}{m}_{l},\\phantom{\\rule{0.25em}{0ex}}{m}_{s}\\right)[\/latex]. For example, the quantum numbers [latex]\\left(2, 1, 0,\\phantom{\\rule{0.25em}{0ex}}-1\/2\\right)[\/latex] completely specify the state of an electron in an atom.<\/p>\n<p id=\"import-auto-id3025617\">Since no two electrons can have the same set of quantum numbers, there are limits to how many of them can be in the same energy state. Note that [latex]n[\/latex] determines the energy state in the absence of a magnetic field. So we first choose [latex]n[\/latex], and then we see how many electrons can be in this energy state or energy level. Consider the [latex]n=1[\/latex] level, for example. The only value [latex]l[\/latex] can have is 0 (see <a href=\"\/contents\/c1f0576f-1366-45d2-8f18-a54b8b35c1c5@10#import-auto-id3013526\" class=\"autogenerated-content\">(Figure)<\/a> for a list of possible values once [latex]n[\/latex] is known), and thus [latex]{m}_{l}[\/latex] can only be 0. The spin projection [latex]{m}_{s}[\/latex] can be either [latex]+1\/2[\/latex] or [latex]-1\/2[\/latex], and so there can be two electrons in the [latex]n=1[\/latex] state. One has quantum numbers [latex]\\left(1, 0, 0,\\phantom{\\rule{0.25em}{0ex}}+1\/2\\right)[\/latex], and the other has [latex]\\left(1, 0, 0,\\phantom{\\rule{0.25em}{0ex}}-1\/2\\right)[\/latex]. <a href=\"#fs-id2930681\" class=\"autogenerated-content\">(Figure)<\/a> illustrates that there can be one or two electrons having [latex]n=1[\/latex], but not three.<\/p>\n<div class=\"bc-figure figure\" id=\"fs-id2930681\">\n<div class=\"bc-figcaption figcaption\">The Pauli exclusion principle explains why some configurations of electrons are allowed while others are not. Since electrons cannot have the same set of quantum numbers, a maximum of two can be in the [latex]n=1[\/latex] level, and a third electron must reside in the higher-energy [latex]n=2[\/latex] level. If there are two electrons in the [latex]n=1[\/latex] level, their spins must be in opposite directions. (More precisely, their spin projections must differ.)<\/div>\n<p><span data-type=\"media\" id=\"fs-id3009617\" data-alt=\"The figure here shows configuration of electrons. At the top, the key shows two purple balls, which depict electrons. The upward directed arrow on the first ball or electron shows its spin is plus one half, and the downward arrow on the second electron shows the opposite spin that is minus one half. Two other sections show the electronic configurations of electrons for two levels, n equal to one and n equal to two. One section shows the allowed configurations of the electron in the n is equal to one and two levels, and the second section for the configurations which are not allowed. In the allowed section, n is equal to two has three vacant shells and one electron in each of the outer two shells, one with spin up and one with spin down; and n is equal to one configuration has two shells containing one each spin up and spin down electron and the three other shells containing combinations of both spins each. For the not allowed section, n is equal to two have all vacant shells and n is equal to one have unevenly balanced electrons in its shells.\"><img src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_02a.jpg\" data-media-type=\"image\/jpg\" alt=\"The figure here shows configuration of electrons. At the top, the key shows two purple balls, which depict electrons. The upward directed arrow on the first ball or electron shows its spin is plus one half, and the downward arrow on the second electron shows the opposite spin that is minus one half. Two other sections show the electronic configurations of electrons for two levels, n equal to one and n equal to two. One section shows the allowed configurations of the electron in the n is equal to one and two levels, and the second section for the configurations which are not allowed. In the allowed section, n is equal to two has three vacant shells and one electron in each of the outer two shells, one with spin up and one with spin down; and n is equal to one configuration has two shells containing one each spin up and spin down electron and the three other shells containing combinations of both spins each. For the not allowed section, n is equal to two have all vacant shells and n is equal to one have unevenly balanced electrons in its shells.\" width=\"250\"><\/span><\/p><\/div>\n<\/div>\n<div class=\"bc-section section\" data-depth=\"1\" id=\"fs-id3286002\">\n<h1 data-type=\"title\">Shells and Subshells<\/h1>\n<p id=\"import-auto-id3143649\">Because of the Pauli exclusion principle, only hydrogen and helium can have all of their electrons in the [latex]n=1[\/latex] state. Lithium (see the periodic table) has three electrons, and so one must be in the [latex]n=2[\/latex] level. This leads to the concept of shells and shell filling. As we progress up in the number of electrons, we go from hydrogen to helium, lithium, beryllium, boron, and so on, and we see that there are limits to the number of electrons for each value of [latex]n[\/latex]. Higher values of the shell [latex]n[\/latex] correspond to higher energies, and they can allow more electrons because of the various combinations of [latex]l,\\phantom{\\rule{0.25em}{0ex}}{m}_{l}[\/latex], and [latex]{m}_{s}[\/latex] that are possible. Each value of the principal quantum number [latex]n[\/latex] thus corresponds to an atomic <span data-type=\"term\">shell<\/span> into which a limited number of electrons can go. Shells and the number of electrons in them determine the physical and chemical properties of atoms, since it is the outermost electrons that interact most with anything outside the atom.<\/p>\n<p id=\"import-auto-id1389362\">The probability clouds of electrons with the lowest value of [latex]l[\/latex] are closest to the nucleus and, thus, more tightly bound. Thus when shells fill, they start with [latex]l=0[\/latex], progress to [latex]l=1[\/latex], and so on. Each value of [latex]l[\/latex] thus corresponds to a <span data-type=\"term\">subshell<\/span>.<\/p>\n<p>The table given below lists symbols traditionally used to denote shells and subshells.<\/p>\n<table summary=\"A three-column table listing the shell n in the first column, the subshell number l in the second column, and the symbol for the subshell in the third column.\">\n<caption><span data-type=\"title\">Shell and Subshell Symbols<\/span><\/caption>\n<thead>\n<tr>\n<th>Shell<\/th>\n<th colspan=\"2\">Subshell<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td data-align=\"center\">[latex]n[\/latex]<\/td>\n<td data-align=\"center\">[latex]l[\/latex]<\/td>\n<td data-align=\"center\"><strong data-effect=\"bold\"><em data-effect=\"italics\">Symbol<\/em><\/strong><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">1<\/td>\n<td data-align=\"center\">0<\/td>\n<td data-align=\"center\">[latex]s[\/latex]<\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">2<\/td>\n<td data-align=\"center\">1<\/td>\n<td data-align=\"center\">[latex]p[\/latex]<\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">3<\/td>\n<td data-align=\"center\">2<\/td>\n<td data-align=\"center\">[latex]d[\/latex]<\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">4<\/td>\n<td data-align=\"center\">3<\/td>\n<td data-align=\"center\">[latex]f[\/latex]<\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">5<\/td>\n<td data-align=\"center\">4<\/td>\n<td data-align=\"center\">[latex]g[\/latex]<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td data-align=\"center\">5<\/td>\n<td data-align=\"center\">[latex]h[\/latex]<\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td data-align=\"center\">6<a data-type=\"footnote-number\" href=\"#footnote1\"><sup>1<\/sup><\/a><\/td>\n<td data-align=\"center\">[latex]i[\/latex]<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p id=\"import-auto-id2025861\">To denote shells and subshells, we write [latex]\\text{nl}[\/latex] with a number for [latex]n[\/latex] and a letter for [latex]l[\/latex]. For example, an electron in the [latex]n=1[\/latex] state must have [latex]l=0[\/latex], and it is denoted as a [latex]1s[\/latex] electron. Two electrons in the <em data-effect=\"italics\">[latex]n=1[\/latex]<\/em> state is denoted as [latex]1{s}^{2}[\/latex]. Another example is an electron in the [latex]n=2[\/latex] state with [latex]l=1[\/latex], written as [latex]2p[\/latex]. The case of three electrons with these quantum numbers is written [latex]2{p}^{3}[\/latex]. This notation, called spectroscopic notation, is generalized as shown in <a href=\"#import-auto-id3354513\" class=\"autogenerated-content\">(Figure)<\/a>.<\/p>\n<div class=\"bc-figure figure\" id=\"import-auto-id3354513\"><span data-type=\"media\" data-alt=\"Diagram illustrating the components of the expression 2 times p to the third power, where 2 is the pricncipal quantum number n, p is the angular momentum quantum number, represented by a script letter l, and the exponent 3 is the number of electrons.\"><img src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_05a.jpg\" data-media-type=\"image\/png\" alt=\"Diagram illustrating the components of the expression 2 times p to the third power, where 2 is the pricncipal quantum number n, p is the angular momentum quantum number, represented by a script letter l, and the exponent 3 is the number of electrons.\" width=\"220\"><\/span><\/div>\n<p id=\"import-auto-id3042712\">Counting the number of possible combinations of quantum numbers allowed by the exclusion principle, we can determine how many electrons it takes to fill each subshell and shell.<\/p>\n<div data-type=\"example\" class=\"textbox examples\" id=\"fs-id3151425\">\n<div data-type=\"title\" class=\"title\">How Many Electrons Can Be in This Shell?<\/div>\n<p id=\"import-auto-id3010071\">List all the possible sets of quantum numbers for the [latex]n=2[\/latex] shell, and determine the number of electrons that can be in the shell and each of its subshells.<\/p>\n<p id=\"import-auto-id1489377\"><strong>Strategy<\/strong><\/p>\n<p id=\"import-auto-id1816930\">Given [latex]n=2[\/latex] for the shell, the rules for quantum numbers limit [latex]l[\/latex] to be 0 or 1. The shell therefore has two subshells, labeled [latex]2s[\/latex] and [latex]2p[\/latex]. Since the lowest [latex]l[\/latex] subshell fills first, we start with the [latex]2s[\/latex] subshell possibilities and then proceed with the [latex]2p[\/latex] subshell.<\/p>\n<p id=\"import-auto-id3109216\"><strong>Solution<\/strong><\/p>\n<p>It is convenient to list the possible quantum numbers in a table, as shown below.<\/p>\n<div class=\"bc-figure figure\"><span data-type=\"media\" id=\"fs-id3230175\" data-alt=\"Image contains a table listing all possible quantum numbers for the n equals 2 shell. The table shows that there are a total of two electrons in the 2 s subshell and six electrons in the 2 p subshell, for a total of eight electrons in the shell.\"><img src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_06a.jpg\" data-media-type=\"image\/jpg\" alt=\"Image contains a table listing all possible quantum numbers for the n equals 2 shell. The table shows that there are a total of two electrons in the 2 s subshell and six electrons in the 2 p subshell, for a total of eight electrons in the shell.\" width=\"350\"><\/span><\/div>\n<p id=\"import-auto-id3176921\"><strong>Discussion<\/strong><\/p>\n<p id=\"import-auto-id2447229\">It is laborious to make a table like this every time we want to know how many electrons can be in a shell or subshell. There exist general rules that are easy to apply, as we shall now see.<\/p>\n<\/div>\n<p id=\"import-auto-id1576041\">The number of electrons that can be in a subshell depends entirely on the value of [latex]l[\/latex]. Once [latex]l[\/latex] is known, there are a fixed number of values of [latex]{m}_{l}[\/latex], each of which can have two values for [latex]{m}_{s}[\/latex] First, since [latex]{m}_{l}[\/latex] goes from <em data-effect=\"italics\">[latex]-l[\/latex]<\/em> to <em data-effect=\"italics\">l<\/em> in steps of 1, there are [latex]2l+1[\/latex] possibilities. This number is multiplied by 2, since each electron can be spin up or spin down. Thus the <em data-effect=\"italics\">maximum number of electrons that can be in a subshell<\/em> is [latex]2\\left(2l+1\\right)[\/latex].<\/p>\n<p id=\"import-auto-id1374635\">For example, the [latex]2s[\/latex] subshell in <a href=\"#fs-id3151425\" class=\"autogenerated-content\">(Figure)<\/a> has a maximum of 2 electrons in it, since [latex]2\\left(2l+1\\right)=2\\left(0+1\\right)=2[\/latex] for this subshell. Similarly, the [latex]2p[\/latex] subshell has a maximum of 6 electrons, since [latex]2\\left(2l+1\\right)=2\\left(2+1\\right)=6[\/latex]. For a shell, the maximum number is the sum of what can fit in the subshells. Some algebra shows that the <em data-effect=\"italics\">maximum number of electrons that can be in a shell<\/em> is [latex]2{n}^{2}[\/latex].<\/p>\n<p id=\"import-auto-id1870898\">For example, for the first shell [latex]n=1[\/latex], and so [latex]2{n}^{2}=2[\/latex]. We have already seen that only two electrons can be in the [latex]n=1[\/latex] shell. Similarly, for the second shell, [latex]n=2[\/latex], and so [latex]2{n}^{2}=8[\/latex]. As found in <a href=\"#fs-id3151425\" class=\"autogenerated-content\">(Figure)<\/a>, the total number of electrons in the [latex]n=2[\/latex] shell is 8.  <\/p>\n<div data-type=\"example\" class=\"textbox examples\" id=\"fs-id3103681\">\n<div data-type=\"title\" class=\"title\">Subshells and Totals for [latex]n=3[\/latex]<\/div>\n<p id=\"import-auto-id3455730\">How many subshells are in the [latex]n=3[\/latex] shell? Identify each subshell, calculate the maximum number of electrons that will fit into each, and verify that the total is [latex]2{n}^{2}[\/latex].<\/p>\n<p id=\"import-auto-id3403574\"><strong>Strategy<\/strong><\/p>\n<p id=\"import-auto-id2448994\">Subshells are determined by the value of [latex]l[\/latex]; thus, we first determine which values of [latex]\\text{l}[\/latex] are allowed, and then we apply the equation \u201cmaximum number of electrons that can be in a subshell [latex]=2\\left(2l+1\\right)[\/latex]\u201d to find the number of electrons in each subshell.<\/p>\n<p><strong>Solution<\/strong><\/p>\n<p id=\"import-auto-id1432067\">Since [latex]n=3[\/latex], we know that [latex]l[\/latex] can be<br>\n[latex]0, 1[\/latex], or<br>\n[latex]2[\/latex]; thus, there are three possible subshells. In standard notation, they are labeled the [latex]3s[\/latex], [latex]3p[\/latex], and [latex]3d[\/latex] subshells. We have already seen that 2 electrons can be in an [latex]s[\/latex] state, and 6 in a [latex]p[\/latex]<em data-effect=\"italics\"> state, but let us use the equation \u201cmaximum number of electrons that can be in a subshell = [latex]2\\left(2l+1\\right)[\/latex]\u201d to calculate the maximum number in each:<\/em><\/p>\n<div data-type=\"equation\" class=\"equation\">[latex]\\begin{array}{l}3s\\phantom{\\rule{0.25em}{0ex}}\\text{has}\\phantom{\\rule{0.25em}{0ex}}l=0\\text{;}\\phantom{\\rule{0.25em}{0ex}}\\text{thus,}\\phantom{\\rule{0.25em}{0ex}}2\\left(2l+1\\right)=2\\left(0+1\\right)=2\\\\ 3p\\phantom{\\rule{0.25em}{0ex}}\\text{has}\\phantom{\\rule{0.25em}{0ex}}l=\\text{1; thus, 2}\\left(2l+1\\right)=2\\left(2+1\\right)=6\\\\ 3d\\phantom{\\rule{0.25em}{0ex}}\\text{has}\\phantom{\\rule{0.25em}{0ex}}l=\\text{2; thus, 2}\\left(2l+1\\right)=2\\left(4+1\\right)=\\text{10}\\\\ \\text{Total}=\\text{18}\\\\ \\left(\\text{in the}\\phantom{\\rule{0.25em}{0ex}}n=\\text{3 shell}\\right)\\end{array}[\/latex]<\/div>\n<p>The equation \u201cmaximum number of electrons that can be in a shell = [latex]2{n}^{2}[\/latex]\u201d gives the maximum number in the [latex]n=3[\/latex] shell to be<\/p>\n<p id=\"import-auto-id3246879\">\n<\/p><div data-type=\"equation\" class=\"equation\" id=\"eip-id3039100\">[latex]\\text{Maximum number of electrons}=2{n}^{2}=2{\\left(3\\right)}^{2}=2\\left(9\\right)=\\text{18.}[\/latex]<\/div>\n<p id=\"import-auto-id3079798\"><strong>Discussion<\/strong><\/p>\n<p id=\"import-auto-id1954742\">The total number of electrons in the three possible subshells is thus the same as the formula [latex]2{n}^{2}[\/latex]. In standard (spectroscopic) notation, a filled [latex]n=3[\/latex] shell is denoted as [latex]3{s}^{2}3{p}^{6}3{d}^{\\text{10}}[\/latex].  Shells do not fill in a simple manner. Before the [latex]n=3[\/latex] shell is completely filled, for example, we begin to find electrons in the [latex]n=4[\/latex] shell.<\/p>\n<\/div>\n<\/div>\n<div class=\"bc-section section\" data-depth=\"1\" id=\"fs-id1909066\">\n<h1 data-type=\"title\">Shell Filling and the Periodic Table<\/h1>\n<p><a href=\"#import-auto-id1526216\" class=\"autogenerated-content\">(Figure)<\/a> shows electron configurations for the first 20 elements in the periodic table, starting with hydrogen and its single electron and ending with calcium. The Pauli exclusion principle determines the maximum number of electrons allowed in each shell and subshell. But the order in which the shells and subshells are filled is complicated because of the large numbers of interactions between electrons.<\/p>\n<table id=\"import-auto-id1526216\" summary=\"Eight-column table listing Elements in column one and Number of electrons (Z) in column 2. Columns 3 through 8 list the ground state configurations for each element. Many of the cells in these columns are blank because some elements have fewer than six ground state configurations. A ditto mark \u201c in a cell indicates that its value is the same as the last cell above it containing a value.\">\n<caption><span data-type=\"title\">Electron Configurations of Elements Hydrogen Through Calcium<\/span><\/caption>\n<thead>\n<tr>\n<th>Element<\/th>\n<th>Number of electrons (Z)<\/th>\n<th colspan=\"6\">Ground state configuration<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td data-align=\"center\">H<\/td>\n<td data-align=\"center\">1<\/td>\n<td>[latex]1{s}^{1}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">He<\/td>\n<td data-align=\"center\">2<\/td>\n<td>[latex]1{s}^{2}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Li<\/td>\n<td data-align=\"center\">3<\/td>\n<td>[latex]1{s}^{2}[\/latex]<\/td>\n<td>[latex]2{s}^{1}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Be<\/td>\n<td data-align=\"center\">4<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">B<\/td>\n<td data-align=\"center\">5<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{1}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">C<\/td>\n<td data-align=\"center\">6<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{2}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">N<\/td>\n<td data-align=\"center\">7<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{3}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">O<\/td>\n<td data-align=\"center\">8<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{4}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">F<\/td>\n<td data-align=\"center\">9<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{5}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Ne<\/td>\n<td data-align=\"center\">10<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{6}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Na<\/td>\n<td data-align=\"center\">11<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]2{s}^{2}[\/latex]<\/td>\n<td>[latex]2{p}^{6}[\/latex]<\/td>\n<td>[latex]3{s}^{1}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Mg<\/td>\n<td data-align=\"center\">12<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Al<\/td>\n<td data-align=\"center\">13<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{1}[\/latex]<\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Si<\/td>\n<td data-align=\"center\">14<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{2}[\/latex]<\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">P<\/td>\n<td data-align=\"center\">15<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{3}[\/latex]<\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">S<\/td>\n<td data-align=\"center\">16<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{4}[\/latex]<\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Cl<\/td>\n<td data-align=\"center\">17<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{5}[\/latex]<\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Ar<\/td>\n<td data-align=\"center\">18<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{6}[\/latex]<\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">K<\/td>\n<td data-align=\"center\">19<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]3{s}^{2}[\/latex]<\/td>\n<td>[latex]3{p}^{6}[\/latex]<\/td>\n<td>[latex]4{s}^{1}[\/latex]<\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Ca<\/td>\n<td data-align=\"center\">20<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td data-align=\"center\">\"<\/td>\n<td>[latex]4{s}^{2}[\/latex]<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p id=\"import-auto-id1617246\">Examining the above table, you can see that as the number of electrons in an atom increases from 1 in hydrogen to 2 in helium and so on, the lowest-energy shell gets filled first\u2014that is, the [latex]n=1[\/latex] shell fills first, and then the [latex]n=2[\/latex] shell begins to fill. Within a shell, the subshells fill starting with the lowest <em data-effect=\"italics\">[latex]l[\/latex]<\/em>, or with the <em data-effect=\"italics\">[latex]s[\/latex]<\/em> subshell, then the [latex]p[\/latex], and so on, usually until all subshells are filled. The first exception to this occurs for potassium, where the [latex]4s[\/latex] subshell begins to fill before any electrons go into the [latex]3d[\/latex] subshell. The next exception is not shown in <a href=\"#import-auto-id1526216\" class=\"autogenerated-content\">(Figure)<\/a>; it occurs for rubidium, where the [latex]5s[\/latex] subshell starts to fill before the [latex]4d[\/latex] subshell. The reason for these exceptions is that [latex]l=0[\/latex] electrons have probability clouds that penetrate closer to the nucleus and, thus, are more tightly bound (lower in energy).<\/p>\n<p id=\"import-auto-id3116313\"><a href=\"#fs-id3068680\" class=\"autogenerated-content\">(Figure)<\/a> shows the periodic table of the elements, through element 118. Of special interest are elements in the main groups, namely, those in the columns numbered 1, 2, 13, 14, 15, 16, 17, and 18.<\/p>\n<div class=\"bc-figure figure\" id=\"fs-id3068680\">\n<div class=\"bc-figcaption figcaption\">Periodic table of the elements (credit: National Institute of Standards and Technology, U.S. Department of Commerce)<\/div>\n<p><span data-type=\"media\" id=\"fs-id2970862\" data-alt=\"This picture shows the periodic table of the elements.\"><img src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_03a.jpg\" data-media-type=\"image\/jpg\" alt=\"This picture shows the periodic table of the elements.\" width=\"400\"><\/span><\/p><\/div>\n<p id=\"import-auto-id2965677\">The number of electrons in the outermost subshell determines the atom\u2019s chemical properties, since it is these electrons that are farthest from the nucleus and thus interact most with other atoms. If the outermost subshell can accept or give up an electron easily, then the atom will be highly reactive chemically. Each group in the periodic table is characterized by its outermost electron configuration. Perhaps the most familiar is Group 18 (Group VIII), the noble gases (helium, neon, argon, etc.). These gases are all characterized by a filled outer subshell that is particularly stable. This means that they have large ionization energies and do not readily give up an electron. Furthermore, if they were to accept an extra electron, it would be in a significantly higher level and thus loosely bound. Chemical reactions often involve sharing electrons. Noble gases can be forced into unstable chemical compounds only under high pressure and temperature.<\/p>\n<p id=\"import-auto-id2398599\">Group 17 (Group VII) contains the halogens, such as fluorine, chlorine, iodine and bromine, each of which has one less electron than a neighboring noble gas. Each halogen has 5 [latex]p[\/latex] electrons (a [latex]{p}^{\\text{5}}[\/latex]  configuration), while the [latex]p[\/latex] subshell can hold 6 electrons. This means the halogens have one vacancy in their outermost subshell. They thus readily accept an extra electron (it becomes tightly bound, closing the shell as in noble gases) and are highly reactive chemically. The halogens are also likely to form singly negative ions, such as [latex]{C1}^{-}[\/latex], fitting an extra electron into the vacancy in the outer subshell. In contrast, alkali metals, such as sodium and potassium, all have a single [latex]s[\/latex] electron in their outermost subshell (an [latex]{s}^{1}[\/latex]<br>\n     configuration) and are members of Group 1 (Group I). These elements easily give up their extra electron and are thus highly reactive chemically. As you might expect, they also tend to form singly positive ions, such as [latex]{\\text{Na}}^{+}[\/latex], by losing their loosely bound outermost electron. They are metals (conductors), because the loosely bound outer electron can move freely.<\/p>\n<p id=\"import-auto-id1431797\">Of course, other groups are also of interest. Carbon, silicon, and germanium, for example, have similar chemistries and are in Group 4 (Group IV). Carbon, in particular, is extraordinary in its ability to form many types of bonds and to be part of long chains, such as inorganic molecules. The large group of what are called transitional elements is characterized by the filling of the [latex]d[\/latex] subshells and crossing of energy levels. Heavier groups, such as the lanthanide series, are more complex\u2014their shells do not fill in simple order. But the groups recognized by chemists such as Mendeleev have an explanation in the substructure of atoms.<\/p>\n<\/div>\n<div data-type=\"note\" class=\"note\" data-has-label=\"true\" data-label=\"\">\n<div data-type=\"title\" class=\"title\">PhET Explorations: Build an Atom<\/div>\n<p id=\"eip-id1815982\">Build an atom out of protons, neutrons, and electrons, and see how the element, charge, and mass change. Then play a game to test your ideas!<\/p>\n<div class=\"bc-figure figure\" id=\"eip-id1399668\">\n<div class=\"bc-figcaption figcaption\"><a href=\"\/resources\/5c21772c30c88ee989a6f25180e504fd3538c472\/build-an-atom_en.jar\">Build an Atom<\/a><\/div>\n<p><span data-type=\"media\" id=\"Phet_module_31.9\" data-alt=\"\"><a href=\"\/resources\/5c21772c30c88ee989a6f25180e504fd3538c472\/build-an-atom_en.jar\" data-type=\"image\"><img src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/PhET_Icon.png\" data-media-type=\"image\/png\" alt=\"\" data-print=\"false\" width=\"450\"><\/a><span data-media-type=\"image\/png\" data-print=\"true\" data-src=\"\/resources\/075500ad9f71890a85fe3f7a4137ac08e2b7907c\/PhET_Icon.png\" data-type=\"image\"><\/span><\/span><\/p><\/div>\n<\/div>\n<div class=\"section-summary\" data-depth=\"1\" id=\"fs-id2017186\">\n<h1 data-type=\"title\">Section Summary<\/h1>\n<ul id=\"fs-id1993103\">\n<li>The state of a system is completely described by a complete set of quantum numbers. This set is written as [latex]\\left(\\mathrm{n, l,}\\phantom{\\rule{0.25em}{0ex}}{m}_{l},\\phantom{\\rule{0.25em}{0ex}}{m}_{s}\\right)[\/latex].<\/li>\n<li id=\"import-auto-id2396692\">The Pauli exclusion principle says that no two electrons can have the same set of quantum numbers; that is, no two electrons can be in the same state.<\/li>\n<li id=\"import-auto-id2409836\">This exclusion limits the number of electrons in atomic shells and subshells. Each value of [latex]n[\/latex] corresponds to a shell, and each value of [latex]l[\/latex] corresponds to a subshell.<\/li>\n<li id=\"import-auto-id2953279\">The maximum number of electrons that can be in a subshell is [latex]2\\left(2l+1\\right)[\/latex].<\/li>\n<li id=\"import-auto-id3043936\">The maximum number of electrons that can be in a shell is [latex]2{n}^{2}[\/latex].<\/li>\n<\/ul>\n<\/div>\n<div class=\"conceptual-questions\" data-depth=\"1\" id=\"fs-id2991416\" data-element-type=\"conceptual-questions\">\n<h1 data-type=\"title\">Conceptual Questions<\/h1>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2929510\" data-element-type=\"conceptual-questions\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1557239\">\n<p id=\"import-auto-id2403115\">Identify the shell, subshell, and number of electrons for the following: (a) [latex]2{p}^{3}[\/latex]. (b) [latex]4{d}^{9}[\/latex]. (c) [latex]3{s}^{1}[\/latex]. (d) [latex]5{g}^{\\text{16}}[\/latex].<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" data-element-type=\"conceptual-questions\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1579144\">\n<p id=\"import-auto-id2978545\">Which of the following are not allowed? State which rule is violated for any that are not allowed. (a) [latex]1{p}^{3}[\/latex] (b) [latex]2{p}^{8}[\/latex](c) [latex]3{g}^{\\text{11}}[\/latex] (d) [latex]4{f}^{2}[\/latex]<\/p>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"problems-exercises\" data-depth=\"1\" id=\"fs-id1435351\" data-element-type=\"problems-exercises\">\n<h1 data-type=\"title\">Problem Exercises<\/h1>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3386479\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3386480\">\n<p id=\"import-auto-id2444624\">(a) How many electrons can be in the [latex]n=4[\/latex] shell?<\/p>\n<p id=\"import-auto-id1598767\">(b) What are its subshells, and how many electrons can be in each?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3402641\">\n<p id=\"import-auto-id1598771\">(a) 32. (b) [latex]2\\phantom{\\rule{0.25em}{0ex}}\\text{in}\\phantom{\\rule{0.25em}{0ex}}s,\\phantom{\\rule{0.25em}{0ex}}\\text{6 in}\\phantom{\\rule{0.25em}{0ex}}p,\\phantom{\\rule{0.25em}{0ex}}\\text{10 in}\\phantom{\\rule{0.25em}{0ex}}d,[\/latex] and 14 in [latex]f[\/latex], for a total of 32.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1616048\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1616049\">\n<p id=\"import-auto-id2435767\">(a) What is the minimum value of 1 for a subshell that has 11 electrons in it? <\/p>\n<p id=\"import-auto-id2435769\">(b) If this subshell is in the<br>\n[latex]n=\\text{5}[\/latex] shell, what is the spectroscopic notation for this atom?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1412034\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1412035\">\n<p id=\"import-auto-id3043928\">(a) If one subshell of an atom has 9 electrons in it, what is the minimum value of [latex]l[\/latex]?  (b) What is the spectroscopic notation for this atom, if this subshell is part of the [latex]n=3[\/latex] shell?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id1539133\">\n<p id=\"import-auto-id1617226\">(a) 2<\/p>\n<p id=\"import-auto-id1617228\">(b) [latex]3{d}^{9}[\/latex]<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2683700\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2683701\">\n<p id=\"import-auto-id1599274\">(a) List all possible sets of quantum numbers [latex]\\left(n,\\phantom{\\rule{0.25em}{0ex}}l,\\phantom{\\rule{0.25em}{0ex}}{m}_{l},\\phantom{\\rule{0.25em}{0ex}}{m}_{s}\\right)[\/latex] for the [latex]n=3[\/latex] shell, and determine the number of electrons that can be in the shell and each of its subshells.<\/p>\n<p id=\"import-auto-id3105697\">(b) Show that the number of electrons in the shell equals [latex]2{n}^{2}[\/latex] and that the number in each subshell is [latex]2\\left(2l+1\\right)[\/latex].<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3355596\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3355597\">\n<p id=\"import-auto-id3026489\">Which of the following spectroscopic notations are not allowed? (a) <\/p>\n[latex]5{s}^{1}[\/latex]\n<p>(b)<br>\n[latex]1{d}^{1}[\/latex]<br>\n(c)<br>\n[latex]4{s}^{3}[\/latex]<br>\n(d)<br>\n[latex]3{p}^{7}[\/latex]<br>\n(e)<br>\n[latex]5{g}^{15}[\/latex]. State which rule is violated for each that is not allowed.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id2668726\">\n<p id=\"import-auto-id3157292\">(b) [latex]n\\ge l[\/latex]  is violated,<\/p>\n<p id=\"fs-id2373165\">(c) cannot have 3 electrons in [latex]s[\/latex]  subshell since<br>\n[latex]3&gt;\\left(2l+1\\right)=2\\phantom{\\rule{0.25em}{0ex}}[\/latex]<\/p>\n<p id=\"fs-id2373168\">(d) cannot have 7 electrons in [latex]p[\/latex]  subshell since<br>\n[latex]7&gt;\\left(2l+1\\right)=2\\left(2+1\\right)=6[\/latex]<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1480219\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1480220\">\n<p id=\"import-auto-id2602609\">Which of the following spectroscopic notations are allowed (that is, which violate none of the rules regarding values of quantum numbers)? (a) [latex]1{s}^{1}[\/latex](b) [latex]1{d}^{3}[\/latex](c) [latex]4{s}^{2}[\/latex] (d) [latex]3{p}^{7}[\/latex](e) [latex]6{h}^{\\text{20}}[\/latex]<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1608615\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1608616\">\n<p id=\"import-auto-id1486422\">(a) Using the Pauli exclusion principle and the rules relating the allowed values of the quantum numbers [latex]\\left(n,\\phantom{\\rule{0.25em}{0ex}}l,\\phantom{\\rule{0.25em}{0ex}}{m}_{l},\\phantom{\\rule{0.25em}{0ex}}{m}_{s}\\right)[\/latex], prove that the maximum number of electrons in a subshell is [latex]2{n}^{2}[\/latex]. <\/p>\n<p id=\"import-auto-id3210276\">(b) In a similar manner, prove that the maximum number of electrons in a shell is 2<em data-effect=\"italics\">n<\/em><sup>2<\/sup>.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id1443947\">\n<p id=\"import-auto-id1528331\">(a) The number of different values of [latex]{m}_{l}[\/latex] is [latex]\u00b1l,\u00b1\\left(l-1\\right),\\text{...,}0[\/latex] for each [latex]l&gt;0[\/latex] and one for [latex]l=0\u21d2\\left(2l+1\\right)\\text{.}[\/latex] Also an overall factor of 2 since each [latex]{m}_{l}[\/latex] can have [latex]{m}_{s}[\/latex] equal to either [latex]+1\/2[\/latex] or [latex]-1\/2\u21d22\\left(2l+1\\right)[\/latex]. <\/p>\n<p id=\"import-auto-id1528334\">(b) for each value of [latex]l[\/latex], you get [latex]2\\left(2l+1\\right)[\/latex]<\/p>\n<p id=\"import-auto-id1889894\">[latex]=\\text{0, 1, 2, ...,}\\left(n\\text{\u20131}\\right)\u21d22\\left\\{\\left[\\left(2\\right)\\left(0\\right)+1\\right]+\\left[\\left(2\\right)\\left(1\\right)+1\\right]+\\text{.}\\text{.}\\text{.}\\text{.}+\\left[\\left(2\\right)\\left(n-1\\right)+1\\right]\\right\\}=\\underset{\\underset{n\\phantom{\\rule{0.25em}{0ex}}\\text{terms}}{\ufe38}}{2\\left[1+3+\\text{.}\\text{.}\\text{.}+\\left(2n-3\\right)+\\left(2n-1\\right)\\right]}[\/latex] to see that the expression in the box is [latex]={n}^{2},[\/latex] imagine taking [latex]\\left(n-1\\right)[\/latex] from the last term and adding it to first term [latex]=2\\left[1+\\left(n\\text{\u20131}\\right)+3+\\text{.}\\text{.}\\text{.}+\\left(2n-3\\right)+\\left(2n-1\\right)\u2013\\left(n-1\\right)\\right]=2\\left[n+3+\\text{.}\\text{.}\\text{.}\\text{.}+\\left(2n-3\\right)+n\\right]\\text{.}[\/latex] Now take [latex]\\left(n-3\\right)[\/latex] from penultimate term and add to the second term [latex]2\\underset{\\underset{n\\phantom{\\rule{0.25em}{0ex}}\\text{terms}}{\ufe38}}{\\left[n+n+\\text{.}\\text{.}\\text{.}+n+n\\right]}={2n}^{2}[\/latex].<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2313136\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2313137\">\n<p id=\"fs-id2313138\"><strong data-effect=\"bold\">Integrated Concepts<\/strong><\/p>\n<p id=\"fs-id2328449\">Estimate the density of a nucleus by calculating the density of a proton, taking it to be a sphere 1.2 fm in diameter. Compare your result with the value estimated in this chapter.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2378469\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2378470\">\n<p id=\"import-auto-id2444200\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2588858\">The electric and magnetic forces on an electron in the CRT in <a href=\"\/contents\/7ecc38ba-f855-43c4-bad7-50c40b70556d@6#fs-id961353\" class=\"autogenerated-content\">(Figure)<\/a> are supposed to be in opposite directions. Verify this by determining the direction of each force for the situation shown. Explain how you obtain the directions (that is, identify the rules used).<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3099218\">\n<p id=\"import-auto-id3063565\">The electric force on the electron is up (toward the positively charged plate). The magnetic force is down (by the RHR).<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3099228\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3099229\">\n<p id=\"import-auto-id1474941\">(a) What is the distance between the slits of a diffraction grating that produces a first-order maximum for the first Balmer line at an angle of [latex]\\text{20.0\u00ba}[\/latex]?<\/p>\n<p id=\"fs-id1590957\">(b) At what angle will the fourth line of the Balmer series appear in first order?<\/p>\n<p id=\"fs-id2305542\">(c) At what angle will the second-order maximum be for the first line?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2378650\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2378651\">\n<p id=\"import-auto-id2929690\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id1464238\">A galaxy moving away from the earth has a speed of<br>\n[latex]\\text{0.0100}c[\/latex]. What wavelength do we observe for an [latex]{n}_{\\text{i}}=7[\/latex] to [latex]{n}_{\\text{f}}=2[\/latex] transition for hydrogen in that galaxy?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3187298\">\n<p id=\"import-auto-id3035430\">401 nm<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3187307\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3187308\">\n<p id=\"import-auto-id2929099\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id1986345\">Calculate the velocity of a star moving relative to the earth if you observe a wavelength of 91.0 nm for ionized hydrogen capturing an electron directly into the lowest orbital (that is, a [latex]{n}_{\\text{i}}=\\infty [\/latex] to [latex]{n}_{\\text{f}}=1[\/latex], or a Lyman series transition).<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3188615\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3188616\">\n<p id=\"import-auto-id2397270\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3090531\">In a Millikan oil-drop experiment using a setup like that in <a href=\"\/contents\/7ecc38ba-f855-43c4-bad7-50c40b70556d@6#fs-id2010482\" class=\"autogenerated-content\">(Figure)<\/a>, a 500-V potential difference is applied to plates separated by 2.50 cm. (a) What is the mass of an oil drop having two extra electrons that is suspended motionless by the field between the plates? (b) What is the diameter of the drop, assuming it is a sphere with the density of olive oil?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id2919072\">\n<p id=\"import-auto-id3357873\">(a) [latex]6\\text{.}\\text{54}\u00d7{\\text{10}}^{-\\text{16}}\\phantom{\\rule{0.25em}{0ex}}\\text{kg}[\/latex]<\/p>\n<p id=\"import-auto-id3025603\">(b) [latex]5\\text{.}\\text{54}\u00d7{\\text{10}}^{-7}\\phantom{\\rule{0.25em}{0ex}}\\text{m}[\/latex]<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1539051\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1539052\">\n<p id=\"import-auto-id3253406\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3148820\">What double-slit separation would produce a first-order maximum at [latex]3\\text{.}\\text{00\u00ba}[\/latex] for 25.0-keV x rays? The small answer indicates that the wave character of x rays is best determined by having them interact with very small objects such as atoms and molecules.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3450401\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3450402\">\n<p id=\"import-auto-id2400659\"><strong>Integrated Concepts <\/strong><\/p>\n<p id=\"eip-id1616692\">In a laboratory experiment designed to duplicate Thomson\u2019s determination of [latex]{q}_{e}\/{m}_{e}[\/latex], a beam of electrons having a velocity of [latex]6\\text{.}\\text{00}\u00d7{\\text{10}}^{7}\\phantom{\\rule{0.25em}{0ex}}\\text{m\/s}[\/latex] enters a [latex]\\text{5.00}\u00d7{\\text{10}}^{-3}\\phantom{\\rule{0.25em}{0ex}}\\text{T}[\/latex] magnetic field. The beam moves perpendicular to the field in a path having a 6.80-cm radius of curvature. Determine [latex]{q}_{e}\/{m}_{e}[\/latex] from these observations, and compare the result with the known value.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id2519902\">\n<p id=\"import-auto-id3163259\">[latex]1\\text{.}\\text{76}\u00d7{\\text{10}}^{\\text{11}}\\phantom{\\rule{0.25em}{0ex}}\\text{C\/kg}[\/latex]<br>\n    , which agrees with the known value of [latex]1\\text{.}\\text{759}\u00d7{\\text{10}}^{\\text{11}}\\phantom{\\rule{0.25em}{0ex}}\\text{C\/kg}[\/latex] to within the precision of the measurement\n    <\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1467272\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1467273\">\n<p id=\"fs-id1467274\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"fs-id1437945\">Find the value of  [latex]l[\/latex], the orbital angular momentum quantum number, for the moon around the earth. The extremely large value obtained implies that it is impossible to tell the difference between adjacent quantized orbits for macroscopic objects.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3065607\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3065608\">\n<p><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2424158\">Particles called muons exist in cosmic rays and can be created in particle accelerators. Muons are very similar to electrons, having the same charge and spin, but they have a mass 207 times greater. When muons are captured by an atom, they orbit just like an electron but with a smaller radius, since the mass in [latex]{a}_{\\text{B}}=\\frac{{h}^{2}}{{4\\pi }^{2}{m}_{e}{\\text{kq}}_{e}^{2}}=\\text{0.529}\u00d7{\\text{10}}^{-\\text{10}}\\phantom{\\rule{0.25em}{0ex}}\\text{m}[\/latex] is 207 [latex]{m}_{e}[\/latex].<\/p>\n<p id=\"import-auto-id3305689\">(a) Calculate the radius of the [latex]n=1[\/latex] orbit for a muon in a uranium ion ([latex]Z=\\text{92}[\/latex]).<\/p>\n<p id=\"import-auto-id3176618\">(b) Compare this with the 7.5-fm radius of a uranium nucleus. Note that since the muon orbits inside the electron, it falls into a hydrogen-like orbit. Since your answer is less than the radius of the nucleus, you can see that the photons emitted as the muon falls into its lowest orbit can give information about the nucleus.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3452608\">\n<p id=\"import-auto-id3063530\">(a) 2.78 fm<\/p>\n<p id=\"import-auto-id3063532\">(b) 0.37 of the nuclear radius.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3568692\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3568693\">\n<p id=\"fs-id3568694\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"fs-id3568697\">Calculate the minimum amount of energy in joules needed to create a population inversion in a helium-neon laser containing [latex]1\\text{.}\\text{00}\u00d7{\\text{10}}^{-4}[\/latex]<br>\n     moles of neon.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3168724\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3168725\">\n<p id=\"import-auto-id3112318\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3305248\">A carbon dioxide laser used in surgery emits infrared radiation with a wavelength of<br>\n[latex]\\text{10.6 \u03bcm}[\/latex]. In 1.00 ms, this laser raised the temperature of [latex]{\\text{1.00 cm}}^{3}[\/latex] of flesh to [latex]\\text{100\u00baC}[\/latex] and evaporated it. <\/p>\n<p id=\"import-auto-id3091780\">(a) How many photons were required? You may assume flesh has the same heat of vaporization as water. (b) What was the minimum power output during the flash?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3066149\">\n<p id=\"import-auto-id2930592\">(a) [latex]1\\text{.}\\text{34}\u00d7{\\text{10}}^{\\text{23}}[\/latex]<\/p>\n<p id=\"import-auto-id3035465\">(b) 2.52 MW<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1545858\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1545859\">\n<p id=\"import-auto-id3035473\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2448326\"> Suppose an MRI scanner uses 100-MHz radio waves.<\/p>\n<p id=\"import-auto-id2627186\">(a) Calculate the photon energy.<\/p>\n<p id=\"import-auto-id2627188\">(b) How does this compare to typical molecular binding energies?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1545878\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1545879\">\n<p id=\"import-auto-id2627194\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2209138\"> (a) An excimer laser used for vision correction emits 193-nm UV. Calculate the photon energy in eV.<\/p>\n<p id=\"import-auto-id2627225\">(b) These photons are used to evaporate corneal tissue, which is very similar to water in its properties. Calculate the amount of energy needed per molecule of water to make the phase change from liquid to gas. That is, divide the heat of vaporization in kJ\/kg by the number of water molecules in a kilogram.<\/p>\n<p id=\"import-auto-id2627230\">(c) Convert this to eV and compare to the photon energy. Discuss the implications.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id1545901\">\n<p id=\"import-auto-id2627234\">(a) 6.42 eV<\/p>\n<p id=\"import-auto-id2627236\">(b) [latex]7.27\u00d7{\\text{10}}^{-\\text{20}}\\phantom{\\rule{0.25em}{0ex}}\\text{J\/molecule}[\/latex]<\/p>\n<p id=\"import-auto-id1539108\">(c) 0.454 eV, 14.1 times less than a single UV photon. Therefore, each photon will evaporate approximately 14 molecules of tissue. This gives the surgeon a rather precise method of removing corneal tissue from the surface of the eye.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1985063\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1985064\">\n<p id=\"import-auto-id3417962\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3036655\"> A neighboring galaxy rotates on its axis so that stars on one side move toward us as fast as 200 km\/s, while those on the other side move away as fast as 200 km\/s. This causes the EM radiation we receive to be Doppler shifted by velocities over the entire range of \u00b1200 km\/s. What range of wavelengths will we observe for the 656.0-nm line in the Balmer series of hydrogen emitted by stars in this galaxy. (This is called line broadening.)<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1985082\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1985083\">\n<p id=\"import-auto-id2662784\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2519593\">A pulsar is a rapidly spinning remnant of a supernova. It rotates on its axis, sweeping hydrogen along with it so that hydrogen on one side moves toward us as fast as 50.0 km\/s, while that on the other side moves away as fast as 50.0 km\/s. This means that the EM radiation we receive will be Doppler shifted over a range of [latex]\u00b1\\text{50}.0 km\/s[\/latex]. What range of wavelengths will we observe for the 91.20-nm line in the Lyman series of hydrogen? (Such line broadening is observed and actually provides part of the evidence for rapid rotation.)<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3303403\">\n<p id=\"import-auto-id3117059\">91.18 nm to 91.22 nm<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3303412\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3303413\">\n<p id=\"import-auto-id3117068\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3080551\"> Prove that the velocity of charged particles moving along a straight path through perpendicular electric and magnetic fields is [latex]v=E\/B[\/latex]. Thus crossed electric and magnetic fields can be used as a velocity selector independent of the charge and mass of the particle involved.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3303454\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3303455\">\n<p id=\"import-auto-id3105945\"><strong>Unreasonable Results<\/strong><\/p>\n<p id=\"eip-id2570741\">(a) What voltage must be applied to an X-ray tube to obtain 0.0100-fm-wavelength X-rays for use in exploring the details of nuclei? (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3303467\">\n<p id=\"import-auto-id3105953\">(a) [latex]1\\text{.}\\text{24}\u00d7{\\text{10}}^{\\text{11}}\\phantom{\\rule{0.25em}{0ex}}\\text{V}[\/latex]<\/p>\n<p id=\"import-auto-id1526234\">(b) The voltage is extremely large compared with any practical value.<\/p>\n<p id=\"import-auto-id2625305\">(c) The assumption of such a short wavelength by this method is unreasonable.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3043155\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3043156\">\n<p id=\"import-auto-id2625313\"><strong>Unreasonable Results<\/strong><\/p>\n<p id=\"eip-id3091254\">A student in a physics laboratory observes a hydrogen spectrum with a diffraction grating for the purpose of measuring the wavelengths of the emitted radiation. In the spectrum, she observes a yellow line and finds its wavelength to be 589 nm. (a) Assuming this is part of the Balmer series, determine [latex]{n}_{\\text{i}}[\/latex], the principal quantum number of the initial state. (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3016578\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3016579\">\n<p id=\"import-auto-id3201432\"><strong>Construct Your Own Problem<\/strong><\/p>\n<p id=\"eip-id3080544\"> The solar corona is so hot that most atoms in it are ionized. Consider a hydrogen-like atom in the corona that has only a single electron. Construct a problem in which you calculate selected spectral energies and wavelengths of the Lyman, Balmer, or other series of this atom that could be used to identify its presence in a very hot gas. You will need to choose the atomic number of the atom, identify the element, and choose which spectral lines to consider.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3016593\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3016594\">\n<p id=\"import-auto-id3192240\"><strong>Construct Your Own Problem<\/strong><\/p>\n<p id=\"eip-id3188190\">Consider the Doppler-shifted hydrogen spectrum received from a rapidly receding galaxy. Construct a problem in which you calculate the energies of selected spectral lines in the Balmer series and examine whether they can be described with a formula like that in the equation [latex]\\frac{1}{\\lambda }=R\\left(\\frac{1}{{n}_{\\text{f}}^{2}}-\\frac{1}{{n}_{\\text{i}}^{2}}\\right)[\/latex], but with a different constant [latex]R[\/latex].<\/p>\n<\/div>\n<\/div>\n<\/div>\n<div data-type=\"footnote-refs\">\n<h2 data-type=\"footnote-title\">Footnotes<\/h2>\n<ol>\n<li><a data-type=\"footnote-ref\" href=\"#footnote-ref1\">1<\/a> It is unusual to deal with subshells having [latex]l[\/latex] greater than 6, but when encountered, they continue to be labeled in alphabetical order.<\/li>\n<\/ol>\n<\/div>\n<div data-type=\"glossary\" class=\"textbox shaded\">\n<h2 data-type=\"glossary-title\">Glossary<\/h2>\n<dl class=\"definition\" id=\"import-auto-id3081439\">\n<dt>atomic number<\/dt>\n<dd id=\"fs-id2520893\">the number of protons in the nucleus of an atom<\/dd>\n<\/dl>\n<dl class=\"definition\" id=\"import-auto-id3081441\">\n<dt>Pauli exclusion principle<\/dt>\n<dd id=\"fs-id2520902\">a principle that states that no two electrons can have the same set of quantum numbers; that is, no two electrons can be in the same state<\/dd>\n<\/dl>\n<dl class=\"definition\" id=\"import-auto-id3081445\">\n<dt>shell<\/dt>\n<dd id=\"fs-id3066054\">a probability cloud for electrons that has a single principal quantum number<\/dd>\n<\/dl>\n<dl class=\"definition\" id=\"import-auto-id3081447\">\n<dt>subshell<\/dt>\n<dd id=\"fs-id3066064\">the probability cloud for electrons that has a single angular momentum quantum number [latex]l[\/latex] <\/dd>\n<\/dl>\n<\/div>\n\n","rendered":"<div class=\"textbox learning-objectives\">\n<h3 itemprop=\"educationalUse\">Learning Objectives<\/h3>\n<ul>\n<li>Define the composition of an atom along with its electrons, neutrons, and protons.<\/li>\n<li>Explain the Pauli exclusion principle and its application to the atom.<\/li>\n<li>Specify the shell and subshell symbols and their positions.<\/li>\n<li>Define the position of electrons in different shells of an atom.<\/li>\n<li>State the position of each element in the periodic table according to shell filling.<\/li>\n<\/ul>\n<\/div>\n<div class=\"bc-section section\" data-depth=\"1\" id=\"fs-id3018172\">\n<h1 data-type=\"title\">Multiple-Electron Atoms<\/h1>\n<p id=\"import-auto-id1487054\">All atoms except hydrogen are multiple-electron atoms. The physical and chemical properties of elements are directly related to the number of electrons a neutral atom has. The periodic table of the elements groups elements with similar properties into columns. This systematic organization is related to the number of electrons in a neutral atom, called the <span data-type=\"term\" id=\"import-auto-id1430981\">atomic number<\/span>, <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-761fd3ca09ad29ba6f86aa02ff540254_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#90;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"12\" style=\"vertical-align: 0px;\" \/>. We shall see in this section that the exclusion principle is key to the underlying explanations, and that it applies far beyond the realm of atomic physics.<\/p>\n<p id=\"import-auto-id3357761\">In 1925, the Austrian physicist Wolfgang Pauli (see <a href=\"#fs-id2688367\" class=\"autogenerated-content\">(Figure)<\/a>) proposed the following rule: No two electrons can have the same set of quantum numbers. That is, no two electrons can be in the same state. This statement is known as the <span data-type=\"term\" id=\"import-auto-id1931568\">Pauli exclusion principle<\/span>, because it excludes electrons from being in the same state. The Pauli exclusion principle is extremely powerful and very broadly applicable. It applies to any identical particles with half-integral intrinsic spin\u2014that is, having <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-533543619cc7b0fdb77116edb50e8d0e_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;&#61;&#49;&#47;&#50;&#44;&#32;&#51;&#47;&#50;&#44;&#32;&#46;&#46;&#46;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"115\" style=\"vertical-align: -5px;\" \/> Thus no two electrons can have the same set of quantum numbers.<\/p>\n<div data-type=\"note\" class=\"note\" data-has-label=\"true\" id=\"fs-id2440737\" data-label=\"\">\n<div data-type=\"title\" class=\"title\">Pauli Exclusion Principle<\/div>\n<p id=\"import-auto-id2024782\">No two electrons can have the same set of quantum numbers. That is, no two electrons can be in the same state.<\/p>\n<\/div>\n<div class=\"bc-figure figure\" id=\"fs-id2688367\">\n<div class=\"bc-figcaption figcaption\">The Austrian physicist Wolfgang Pauli (1900\u20131958) played a major role in the development of quantum mechanics. He proposed the exclusion principle; hypothesized the existence of an important particle, called the neutrino, before it was directly observed; made fundamental contributions to several areas of theoretical physics; and influenced many students who went on to do important work of their own. (credit: Nobel Foundation, via Wikimedia Commons)<\/div>\n<p><span data-type=\"media\" id=\"fs-id3177781\" data-alt=\"A black and white portrait of Austrian physicist Wolfgang Pauli.\"><img decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_01a.jpg\" data-media-type=\"image\/jpg\" alt=\"A black and white portrait of Austrian physicist Wolfgang Pauli.\" width=\"210\" \/><\/span><\/p>\n<\/div>\n<p id=\"import-auto-id3105452\">Let us examine how the exclusion principle applies to electrons in atoms. The quantum numbers involved were defined in <a href=\"\/contents\/c1f0576f-1366-45d2-8f18-a54b8b35c1c5@10\">Quantum Numbers and Rules<\/a> as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-dcbe5f96f52637ea9cd3236061a423d6_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#109;&#97;&#116;&#104;&#114;&#109;&#123;&#110;&#44;&#32;&#108;&#44;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#108;&#125;&#92;&#109;&#97;&#116;&#104;&#114;&#109;&#123;&#44;&#32;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"17\" width=\"68\" style=\"vertical-align: -4px;\" \/>, and <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-39d2d5cd720dde70463c6cd7244570a8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"22\" style=\"vertical-align: -3px;\" \/>. Since <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/> is always <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-872abde626b8cdf8e983a3345ee98925_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#47;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"25\" style=\"vertical-align: -5px;\" \/> for electrons, it is redundant to list <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/>, and so we omit it and specify the state of an electron by a set of four numbers <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e334b8700eb5e85cda0ca3221db793d6_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#108;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#108;&#125;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#115;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"108\" style=\"vertical-align: -4px;\" \/>. For example, the quantum numbers <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b450c87d606fc0eb45eb6a041a72cfec_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#44;&#32;&#49;&#44;&#32;&#48;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#45;&#49;&#47;&#50;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"115\" style=\"vertical-align: -5px;\" \/> completely specify the state of an electron in an atom.<\/p>\n<p id=\"import-auto-id3025617\">Since no two electrons can have the same set of quantum numbers, there are limits to how many of them can be in the same energy state. Note that <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/> determines the energy state in the absence of a magnetic field. So we first choose <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/>, and then we see how many electrons can be in this energy state or energy level. Consider the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> level, for example. The only value <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> can have is 0 (see <a href=\"\/contents\/c1f0576f-1366-45d2-8f18-a54b8b35c1c5@10#import-auto-id3013526\" class=\"autogenerated-content\">(Figure)<\/a> for a list of possible values once <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/> is known), and thus <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-76732a572f6c9fdce08b5d74dd7aced4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"20\" style=\"vertical-align: -3px;\" \/> can only be 0. The spin projection <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-39d2d5cd720dde70463c6cd7244570a8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"22\" style=\"vertical-align: -3px;\" \/> can be either <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-eda3ca21b30ce35ac8b10ebf3597bb3d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#43;&#49;&#47;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"40\" style=\"vertical-align: -5px;\" \/> or <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b5205e45813b524be8d323d4b2d0fade_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#45;&#49;&#47;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"39\" style=\"vertical-align: -5px;\" \/>, and so there can be two electrons in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> state. One has quantum numbers <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7947e33c24e3cef4b57f38279ec01dc3_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#49;&#44;&#32;&#48;&#44;&#32;&#48;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#43;&#49;&#47;&#50;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"115\" style=\"vertical-align: -5px;\" \/>, and the other has <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e9641517c65129130a9336d4d44807ab_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#49;&#44;&#32;&#48;&#44;&#32;&#48;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#45;&#49;&#47;&#50;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"115\" style=\"vertical-align: -5px;\" \/>. <a href=\"#fs-id2930681\" class=\"autogenerated-content\">(Figure)<\/a> illustrates that there can be one or two electrons having <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/>, but not three.<\/p>\n<div class=\"bc-figure figure\" id=\"fs-id2930681\">\n<div class=\"bc-figcaption figcaption\">The Pauli exclusion principle explains why some configurations of electrons are allowed while others are not. Since electrons cannot have the same set of quantum numbers, a maximum of two can be in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> level, and a third electron must reside in the higher-energy <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> level. If there are two electrons in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> level, their spins must be in opposite directions. (More precisely, their spin projections must differ.)<\/div>\n<p><span data-type=\"media\" id=\"fs-id3009617\" data-alt=\"The figure here shows configuration of electrons. At the top, the key shows two purple balls, which depict electrons. The upward directed arrow on the first ball or electron shows its spin is plus one half, and the downward arrow on the second electron shows the opposite spin that is minus one half. Two other sections show the electronic configurations of electrons for two levels, n equal to one and n equal to two. One section shows the allowed configurations of the electron in the n is equal to one and two levels, and the second section for the configurations which are not allowed. In the allowed section, n is equal to two has three vacant shells and one electron in each of the outer two shells, one with spin up and one with spin down; and n is equal to one configuration has two shells containing one each spin up and spin down electron and the three other shells containing combinations of both spins each. For the not allowed section, n is equal to two have all vacant shells and n is equal to one have unevenly balanced electrons in its shells.\"><img decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_02a.jpg\" data-media-type=\"image\/jpg\" alt=\"The figure here shows configuration of electrons. At the top, the key shows two purple balls, which depict electrons. The upward directed arrow on the first ball or electron shows its spin is plus one half, and the downward arrow on the second electron shows the opposite spin that is minus one half. Two other sections show the electronic configurations of electrons for two levels, n equal to one and n equal to two. One section shows the allowed configurations of the electron in the n is equal to one and two levels, and the second section for the configurations which are not allowed. In the allowed section, n is equal to two has three vacant shells and one electron in each of the outer two shells, one with spin up and one with spin down; and n is equal to one configuration has two shells containing one each spin up and spin down electron and the three other shells containing combinations of both spins each. For the not allowed section, n is equal to two have all vacant shells and n is equal to one have unevenly balanced electrons in its shells.\" width=\"250\" \/><\/span><\/p>\n<\/div>\n<\/div>\n<div class=\"bc-section section\" data-depth=\"1\" id=\"fs-id3286002\">\n<h1 data-type=\"title\">Shells and Subshells<\/h1>\n<p id=\"import-auto-id3143649\">Because of the Pauli exclusion principle, only hydrogen and helium can have all of their electrons in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> state. Lithium (see the periodic table) has three electrons, and so one must be in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> level. This leads to the concept of shells and shell filling. As we progress up in the number of electrons, we go from hydrogen to helium, lithium, beryllium, boron, and so on, and we see that there are limits to the number of electrons for each value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/>. Higher values of the shell <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/> correspond to higher energies, and they can allow more electrons because of the various combinations of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-46330c730c06806e3686f62d8197d506_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"17\" width=\"38\" style=\"vertical-align: -4px;\" \/>, and <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-39d2d5cd720dde70463c6cd7244570a8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"22\" style=\"vertical-align: -3px;\" \/> that are possible. Each value of the principal quantum number <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/> thus corresponds to an atomic <span data-type=\"term\">shell<\/span> into which a limited number of electrons can go. Shells and the number of electrons in them determine the physical and chemical properties of atoms, since it is the outermost electrons that interact most with anything outside the atom.<\/p>\n<p id=\"import-auto-id1389362\">The probability clouds of electrons with the lowest value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> are closest to the nucleus and, thus, more tightly bound. Thus when shells fill, they start with <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7c22a41593074aeca243cd53d9dd6077_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#61;&#48;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"38\" style=\"vertical-align: 0px;\" \/>, progress to <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5a20249cd06149045d2aaca6012bd789_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"14\" width=\"37\" style=\"vertical-align: -1px;\" \/>, and so on. Each value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> thus corresponds to a <span data-type=\"term\">subshell<\/span>.<\/p>\n<p>The table given below lists symbols traditionally used to denote shells and subshells.<\/p>\n<table summary=\"A three-column table listing the shell n in the first column, the subshell number l in the second column, and the symbol for the subshell in the third column.\">\n<caption><span data-type=\"title\">Shell and Subshell Symbols<\/span><\/caption>\n<thead>\n<tr>\n<th>Shell<\/th>\n<th colspan=\"2\">Subshell<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/><\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/><\/td>\n<td data-align=\"center\"><strong data-effect=\"bold\"><em data-effect=\"italics\">Symbol<\/em><\/strong><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">1<\/td>\n<td data-align=\"center\">0<\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">2<\/td>\n<td data-align=\"center\">1<\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3bf85f1087e9fbed3a319341134ac1a2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"10\" style=\"vertical-align: -4px;\" \/><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">3<\/td>\n<td data-align=\"center\">2<\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4e8716946f6a868f015e0d62f28bc540_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#100;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"10\" style=\"vertical-align: 0px;\" \/><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">4<\/td>\n<td data-align=\"center\">3<\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-9c09a708375fde2676da319bcdfe8b24_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#102;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"10\" style=\"vertical-align: -4px;\" \/><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">5<\/td>\n<td data-align=\"center\">4<\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-d208fd391fa57c168dc0f151de829fee_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#103;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"9\" style=\"vertical-align: -4px;\" \/><\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td data-align=\"center\">5<\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-14b463d0ecd5b350ced6cf1d6a12eef3_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#104;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"10\" style=\"vertical-align: 0px;\" \/><\/td>\n<\/tr>\n<tr>\n<td><\/td>\n<td data-align=\"center\">6<a data-type=\"footnote-number\" href=\"#footnote1\"><sup>1<\/sup><\/a><\/td>\n<td data-align=\"center\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-695d9d59bd04859c6c99e7feb11daab6_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#105;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"6\" style=\"vertical-align: 0px;\" \/><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p id=\"import-auto-id2025861\">To denote shells and subshells, we write <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-48ab16cd584e70a524f502b0b2e05c42_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#110;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"15\" style=\"vertical-align: 0px;\" \/> with a number for <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/> and a letter for <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/>. For example, an electron in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> state must have <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7c22a41593074aeca243cd53d9dd6077_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#61;&#48;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"38\" style=\"vertical-align: 0px;\" \/>, and it is denoted as a <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-6a15408a913c156471f72804d4d69ecd_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"16\" style=\"vertical-align: -1px;\" \/> electron. Two electrons in the <em data-effect=\"italics\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/><\/em> state is denoted as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5f2737fcc2840003f749fc39fb70ef46_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"23\" style=\"vertical-align: -1px;\" \/>. Another example is an electron in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> state with <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5a20249cd06149045d2aaca6012bd789_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"14\" width=\"37\" style=\"vertical-align: -1px;\" \/>, written as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4b6bb28b8a01f4d4749590c9b0206843_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"18\" style=\"vertical-align: -4px;\" \/>. The case of three electrons with these quantum numbers is written <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e7ca8fad5fb1133f77e8f4707832864d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/>. This notation, called spectroscopic notation, is generalized as shown in <a href=\"#import-auto-id3354513\" class=\"autogenerated-content\">(Figure)<\/a>.<\/p>\n<div class=\"bc-figure figure\" id=\"import-auto-id3354513\"><span data-type=\"media\" data-alt=\"Diagram illustrating the components of the expression 2 times p to the third power, where 2 is the pricncipal quantum number n, p is the angular momentum quantum number, represented by a script letter l, and the exponent 3 is the number of electrons.\"><img decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_05a.jpg\" data-media-type=\"image\/png\" alt=\"Diagram illustrating the components of the expression 2 times p to the third power, where 2 is the pricncipal quantum number n, p is the angular momentum quantum number, represented by a script letter l, and the exponent 3 is the number of electrons.\" width=\"220\" \/><\/span><\/div>\n<p id=\"import-auto-id3042712\">Counting the number of possible combinations of quantum numbers allowed by the exclusion principle, we can determine how many electrons it takes to fill each subshell and shell.<\/p>\n<div data-type=\"example\" class=\"textbox examples\" id=\"fs-id3151425\">\n<div data-type=\"title\" class=\"title\">How Many Electrons Can Be in This Shell?<\/div>\n<p id=\"import-auto-id3010071\">List all the possible sets of quantum numbers for the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> shell, and determine the number of electrons that can be in the shell and each of its subshells.<\/p>\n<p id=\"import-auto-id1489377\"><strong>Strategy<\/strong><\/p>\n<p id=\"import-auto-id1816930\">Given <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> for the shell, the rules for quantum numbers limit <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> to be 0 or 1. The shell therefore has two subshells, labeled <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8bb22f20757e34dfdf5a80d68221af19_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"17\" style=\"vertical-align: 0px;\" \/> and <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4b6bb28b8a01f4d4749590c9b0206843_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"18\" style=\"vertical-align: -4px;\" \/>. Since the lowest <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> subshell fills first, we start with the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8bb22f20757e34dfdf5a80d68221af19_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"17\" style=\"vertical-align: 0px;\" \/> subshell possibilities and then proceed with the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4b6bb28b8a01f4d4749590c9b0206843_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"18\" style=\"vertical-align: -4px;\" \/> subshell.<\/p>\n<p id=\"import-auto-id3109216\"><strong>Solution<\/strong><\/p>\n<p>It is convenient to list the possible quantum numbers in a table, as shown below.<\/p>\n<div class=\"bc-figure figure\"><span data-type=\"media\" id=\"fs-id3230175\" data-alt=\"Image contains a table listing all possible quantum numbers for the n equals 2 shell. The table shows that there are a total of two electrons in the 2 s subshell and six electrons in the 2 p subshell, for a total of eight electrons in the shell.\"><img decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_06a.jpg\" data-media-type=\"image\/jpg\" alt=\"Image contains a table listing all possible quantum numbers for the n equals 2 shell. The table shows that there are a total of two electrons in the 2 s subshell and six electrons in the 2 p subshell, for a total of eight electrons in the shell.\" width=\"350\" \/><\/span><\/div>\n<p id=\"import-auto-id3176921\"><strong>Discussion<\/strong><\/p>\n<p id=\"import-auto-id2447229\">It is laborious to make a table like this every time we want to know how many electrons can be in a shell or subshell. There exist general rules that are easy to apply, as we shall now see.<\/p>\n<\/div>\n<p id=\"import-auto-id1576041\">The number of electrons that can be in a subshell depends entirely on the value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/>. Once <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> is known, there are a fixed number of values of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-76732a572f6c9fdce08b5d74dd7aced4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"20\" style=\"vertical-align: -3px;\" \/>, each of which can have two values for <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-39d2d5cd720dde70463c6cd7244570a8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"22\" style=\"vertical-align: -3px;\" \/> First, since <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-76732a572f6c9fdce08b5d74dd7aced4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"20\" style=\"vertical-align: -3px;\" \/> goes from <em data-effect=\"italics\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-cee1d4ddc1db3b3f4a71439b73ec5e90_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#45;&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"18\" style=\"vertical-align: 0px;\" \/><\/em> to <em data-effect=\"italics\">l<\/em> in steps of 1, there are <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-19dbd549aff57c8d7aa093ae962ee041_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#108;&#43;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"44\" style=\"vertical-align: -2px;\" \/> possibilities. This number is multiplied by 2, since each electron can be spin up or spin down. Thus the <em data-effect=\"italics\">maximum number of electrons that can be in a subshell<\/em> is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-963e5430880faa9445b64b5a5cea52b9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"70\" style=\"vertical-align: -4px;\" \/>.<\/p>\n<p id=\"import-auto-id1374635\">For example, the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8bb22f20757e34dfdf5a80d68221af19_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"17\" style=\"vertical-align: 0px;\" \/> subshell in <a href=\"#fs-id3151425\" class=\"autogenerated-content\">(Figure)<\/a> has a maximum of 2 electrons in it, since <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-86b06b6f37d1d2ccd8fa066fedb336e2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#48;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"191\" style=\"vertical-align: -4px;\" \/> for this subshell. Similarly, the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4b6bb28b8a01f4d4749590c9b0206843_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"18\" style=\"vertical-align: -4px;\" \/> subshell has a maximum of 6 electrons, since <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-79d97252e2411e73cb3178f1b61219b7_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#54;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"192\" style=\"vertical-align: -4px;\" \/>. For a shell, the maximum number is the sum of what can fit in the subshells. Some algebra shows that the <em data-effect=\"italics\">maximum number of electrons that can be in a shell<\/em> is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/>.<\/p>\n<p id=\"import-auto-id1870898\">For example, for the first shell <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/>, and so <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b04875f732706e6b179d5941cd569e63_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"59\" style=\"vertical-align: 0px;\" \/>. We have already seen that only two electrons can be in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> shell. Similarly, for the second shell, <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/>, and so <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a90c89f40e712fc304bf6708a90d3d51_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;&#61;&#56;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"60\" style=\"vertical-align: 0px;\" \/>. As found in <a href=\"#fs-id3151425\" class=\"autogenerated-content\">(Figure)<\/a>, the total number of electrons in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> shell is 8.  <\/p>\n<div data-type=\"example\" class=\"textbox examples\" id=\"fs-id3103681\">\n<div data-type=\"title\" class=\"title\">Subshells and Totals for <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/><\/div>\n<p id=\"import-auto-id3455730\">How many subshells are in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/> shell? Identify each subshell, calculate the maximum number of electrons that will fit into each, and verify that the total is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/>.<\/p>\n<p id=\"import-auto-id3403574\"><strong>Strategy<\/strong><\/p>\n<p id=\"import-auto-id2448994\">Subshells are determined by the value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/>; thus, we first determine which values of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-6df85ab48b8af2edf2759d7a4bb6eea4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> are allowed, and then we apply the equation \u201cmaximum number of electrons that can be in a subshell <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e520f990dec5fd295b02394c5f0cf4c7_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"89\" style=\"vertical-align: -4px;\" \/>\u201d to find the number of electrons in each subshell.<\/p>\n<p><strong>Solution<\/strong><\/p>\n<p id=\"import-auto-id1432067\">Since <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/>, we know that <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> can be<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-77d74e4b5f9f25e57363675c8434aed5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#48;&#44;&#32;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"25\" style=\"vertical-align: -4px;\" \/>, or<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e584dd0bab4e6c8efc164939c28db757_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"8\" style=\"vertical-align: 0px;\" \/>; thus, there are three possible subshells. In standard notation, they are labeled the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-971fd3920c01162aed758d3efb7f892d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"17\" style=\"vertical-align: 0px;\" \/>, <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a218bbe26494417ea455bf1480feb12a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"18\" style=\"vertical-align: -4px;\" \/>, and <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-6a2a590ad7ecb22e27ff712a5abb96ff_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#100;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"19\" style=\"vertical-align: 0px;\" \/> subshells. We have already seen that 2 electrons can be in an <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/> state, and 6 in a <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3bf85f1087e9fbed3a319341134ac1a2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"10\" style=\"vertical-align: -4px;\" \/><em data-effect=\"italics\"> state, but let us use the equation \u201cmaximum number of electrons that can be in a subshell = <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-963e5430880faa9445b64b5a5cea52b9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"70\" style=\"vertical-align: -4px;\" \/>\u201d to calculate the maximum number in each:<\/em><\/p>\n<div data-type=\"equation\" class=\"equation\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-cf7039875fdf5de94f8610cea87430d7_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#98;&#101;&#103;&#105;&#110;&#123;&#97;&#114;&#114;&#97;&#121;&#125;&#123;&#108;&#125;&#51;&#115;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#104;&#97;&#115;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#108;&#61;&#48;&#92;&#116;&#101;&#120;&#116;&#123;&#59;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#116;&#104;&#117;&#115;&#44;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#48;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#92;&#32;&#51;&#112;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#104;&#97;&#115;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#108;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#59;&#32;&#116;&#104;&#117;&#115;&#44;&#32;&#50;&#125;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#54;&#92;&#92;&#32;&#51;&#100;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#104;&#97;&#115;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#108;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#50;&#59;&#32;&#116;&#104;&#117;&#115;&#44;&#32;&#50;&#125;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#52;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#92;&#92;&#32;&#92;&#116;&#101;&#120;&#116;&#123;&#84;&#111;&#116;&#97;&#108;&#125;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#56;&#125;&#92;&#92;&#32;&#92;&#108;&#101;&#102;&#116;&#40;&#92;&#116;&#101;&#120;&#116;&#123;&#105;&#110;&#32;&#116;&#104;&#101;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#110;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#51;&#32;&#115;&#104;&#101;&#108;&#108;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#101;&#110;&#100;&#123;&#97;&#114;&#114;&#97;&#121;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"106\" width=\"347\" style=\"vertical-align: -48px;\" \/><\/div>\n<p>The equation \u201cmaximum number of electrons that can be in a shell = <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/>\u201d gives the maximum number in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/> shell to be<\/p>\n<p id=\"import-auto-id3246879\">\n<div data-type=\"equation\" class=\"equation\" id=\"eip-id3039100\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-aa6afa9d11af6931cde79f5d3ffa42f6_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#77;&#97;&#120;&#105;&#109;&#117;&#109;&#32;&#110;&#117;&#109;&#98;&#101;&#114;&#32;&#111;&#102;&#32;&#101;&#108;&#101;&#99;&#116;&#114;&#111;&#110;&#115;&#125;&#61;&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;&#61;&#50;&#123;&#92;&#108;&#101;&#102;&#116;&#40;&#51;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#125;&#94;&#123;&#50;&#125;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#57;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#56;&#46;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"21\" width=\"454\" style=\"vertical-align: -4px;\" \/><\/div>\n<p id=\"import-auto-id3079798\"><strong>Discussion<\/strong><\/p>\n<p id=\"import-auto-id1954742\">The total number of electrons in the three possible subshells is thus the same as the formula <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/>. In standard (spectroscopic) notation, a filled <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/> shell is denoted as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-2b4f8901c0c13e7216ae1542c81f21d1_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;&#51;&#123;&#112;&#125;&#94;&#123;&#54;&#125;&#51;&#123;&#100;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"82\" style=\"vertical-align: -4px;\" \/>.  Shells do not fill in a simple manner. Before the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/> shell is completely filled, for example, we begin to find electrons in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3d48be04aadb63e5661f86d0948d7553_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#52;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"43\" style=\"vertical-align: -1px;\" \/> shell.<\/p>\n<\/div>\n<\/div>\n<div class=\"bc-section section\" data-depth=\"1\" id=\"fs-id1909066\">\n<h1 data-type=\"title\">Shell Filling and the Periodic Table<\/h1>\n<p><a href=\"#import-auto-id1526216\" class=\"autogenerated-content\">(Figure)<\/a> shows electron configurations for the first 20 elements in the periodic table, starting with hydrogen and its single electron and ending with calcium. The Pauli exclusion principle determines the maximum number of electrons allowed in each shell and subshell. But the order in which the shells and subshells are filled is complicated because of the large numbers of interactions between electrons.<\/p>\n<table id=\"import-auto-id1526216\" summary=\"Eight-column table listing Elements in column one and Number of electrons (Z) in column 2. Columns 3 through 8 list the ground state configurations for each element. Many of the cells in these columns are blank because some elements have fewer than six ground state configurations. A ditto mark \u201c in a cell indicates that its value is the same as the last cell above it containing a value.\">\n<caption><span data-type=\"title\">Electron Configurations of Elements Hydrogen Through Calcium<\/span><\/caption>\n<thead>\n<tr>\n<th>Element<\/th>\n<th>Number of electrons (Z)<\/th>\n<th colspan=\"6\">Ground state configuration<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td data-align=\"center\">H<\/td>\n<td data-align=\"center\">1<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7f95021541ee4b92dd6d70a3c9fe6aab_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"22\" style=\"vertical-align: -1px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">He<\/td>\n<td data-align=\"center\">2<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5f2737fcc2840003f749fc39fb70ef46_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"23\" style=\"vertical-align: -1px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Li<\/td>\n<td data-align=\"center\">3<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5f2737fcc2840003f749fc39fb70ef46_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"23\" style=\"vertical-align: -1px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-d459b47f8ad978b119b6f12a5929ed1e_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"23\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Be<\/td>\n<td data-align=\"center\">4<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">B<\/td>\n<td data-align=\"center\">5<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-1c8530f5d7ce1fecee2ef140a61772e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"24\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">C<\/td>\n<td data-align=\"center\">6<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-33d8f94b15ddc6dfc8d5e74c37f6a8db_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">N<\/td>\n<td data-align=\"center\">7<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e7ca8fad5fb1133f77e8f4707832864d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">O<\/td>\n<td data-align=\"center\">8<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5b4523ae3ef38d56f4fbb90e0808c842_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#52;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">F<\/td>\n<td data-align=\"center\">9<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4a500fdd39312772c9fd38c36fe5ccb7_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#53;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Ne<\/td>\n<td data-align=\"center\">10<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e02e99b7948a186273fcf6778583246c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#54;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Na<\/td>\n<td data-align=\"center\">11<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b70bde5bbfdc0efe203b947d1db695e5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e02e99b7948a186273fcf6778583246c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#54;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-98374c605ed7eece1829acd5834dc4b5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"23\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Mg<\/td>\n<td data-align=\"center\">12<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Al<\/td>\n<td data-align=\"center\">13<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-6dd96f22ee6b2e58f2d81bf1befb37fb_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"24\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Si<\/td>\n<td data-align=\"center\">14<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-45425a58ac1894e1b2a28ce757128967_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">P<\/td>\n<td data-align=\"center\">15<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e9871b648bc7ac314dc8b164c870b2b4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">S<\/td>\n<td data-align=\"center\">16<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e8bb8ff971813f942fa91115797ef20c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#52;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Cl<\/td>\n<td data-align=\"center\">17<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-43ff690433be89bab584a9f9c99b6486_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#53;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Ar<\/td>\n<td data-align=\"center\">18<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-17a36111c1b71bfb0ca60483dd4f4655_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#54;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">K<\/td>\n<td data-align=\"center\">19<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ffa8f4db4351db18635ca7c7e7b5c25a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"24\" style=\"vertical-align: 0px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-17a36111c1b71bfb0ca60483dd4f4655_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#54;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e7b3b2dca19ac8d16104baff47c64adc_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"23\" style=\"vertical-align: -1px;\" \/><\/td>\n<\/tr>\n<tr>\n<td data-align=\"center\">Ca<\/td>\n<td data-align=\"center\">20<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td data-align=\"center\">&#8220;<\/td>\n<td><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-f1c3a906930cb21599b0821bc4943c47_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"24\" style=\"vertical-align: -1px;\" \/><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p id=\"import-auto-id1617246\">Examining the above table, you can see that as the number of electrons in an atom increases from 1 in hydrogen to 2 in helium and so on, the lowest-energy shell gets filled first\u2014that is, the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> shell fills first, and then the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8b4c6cd9d27ba344abe355a47d378bb2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"42\" style=\"vertical-align: 0px;\" \/> shell begins to fill. Within a shell, the subshells fill starting with the lowest <em data-effect=\"italics\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/><\/em>, or with the <em data-effect=\"italics\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/><\/em> subshell, then the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3bf85f1087e9fbed3a319341134ac1a2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"10\" style=\"vertical-align: -4px;\" \/>, and so on, usually until all subshells are filled. The first exception to this occurs for potassium, where the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-42ad4ddcafe32d5516f0e27b1020e663_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"17\" style=\"vertical-align: -1px;\" \/> subshell begins to fill before any electrons go into the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-6a2a590ad7ecb22e27ff712a5abb96ff_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#100;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"19\" style=\"vertical-align: 0px;\" \/> subshell. The next exception is not shown in <a href=\"#import-auto-id1526216\" class=\"autogenerated-content\">(Figure)<\/a>; it occurs for rubidium, where the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-737d8358d1965e9dd9ff458717833d40_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#53;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"17\" style=\"vertical-align: 0px;\" \/> subshell starts to fill before the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-903866ba81ac323f4b5f1fe1d00e2049_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#100;\" title=\"Rendered by QuickLaTeX.com\" height=\"14\" width=\"19\" style=\"vertical-align: -1px;\" \/> subshell. The reason for these exceptions is that <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7c22a41593074aeca243cd53d9dd6077_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#61;&#48;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"38\" style=\"vertical-align: 0px;\" \/> electrons have probability clouds that penetrate closer to the nucleus and, thus, are more tightly bound (lower in energy).<\/p>\n<p id=\"import-auto-id3116313\"><a href=\"#fs-id3068680\" class=\"autogenerated-content\">(Figure)<\/a> shows the periodic table of the elements, through element 118. Of special interest are elements in the main groups, namely, those in the columns numbered 1, 2, 13, 14, 15, 16, 17, and 18.<\/p>\n<div class=\"bc-figure figure\" id=\"fs-id3068680\">\n<div class=\"bc-figcaption figcaption\">Periodic table of the elements (credit: National Institute of Standards and Technology, U.S. Department of Commerce)<\/div>\n<p><span data-type=\"media\" id=\"fs-id2970862\" data-alt=\"This picture shows the periodic table of the elements.\"><img decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/Figure_31_09_03a.jpg\" data-media-type=\"image\/jpg\" alt=\"This picture shows the periodic table of the elements.\" width=\"400\" \/><\/span><\/p>\n<\/div>\n<p id=\"import-auto-id2965677\">The number of electrons in the outermost subshell determines the atom\u2019s chemical properties, since it is these electrons that are farthest from the nucleus and thus interact most with other atoms. If the outermost subshell can accept or give up an electron easily, then the atom will be highly reactive chemically. Each group in the periodic table is characterized by its outermost electron configuration. Perhaps the most familiar is Group 18 (Group VIII), the noble gases (helium, neon, argon, etc.). These gases are all characterized by a filled outer subshell that is particularly stable. This means that they have large ionization energies and do not readily give up an electron. Furthermore, if they were to accept an extra electron, it would be in a significantly higher level and thus loosely bound. Chemical reactions often involve sharing electrons. Noble gases can be forced into unstable chemical compounds only under high pressure and temperature.<\/p>\n<p id=\"import-auto-id2398599\">Group 17 (Group VII) contains the halogens, such as fluorine, chlorine, iodine and bromine, each of which has one less electron than a neighboring noble gas. Each halogen has 5 <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3bf85f1087e9fbed3a319341134ac1a2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"10\" style=\"vertical-align: -4px;\" \/> electrons (a <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-dcdc0e2498b672c4855e5bfe62080872_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#112;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#53;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"17\" style=\"vertical-align: -4px;\" \/>  configuration), while the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3bf85f1087e9fbed3a319341134ac1a2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"10\" style=\"vertical-align: -4px;\" \/> subshell can hold 6 electrons. This means the halogens have one vacancy in their outermost subshell. They thus readily accept an extra electron (it becomes tightly bound, closing the shell as in noble gases) and are highly reactive chemically. The halogens are also likely to form singly negative ions, such as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-2ef4dd7afd697a8a695f67897d708d6c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#67;&#49;&#125;&#94;&#123;&#45;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"33\" style=\"vertical-align: -1px;\" \/>, fitting an extra electron into the vacancy in the outer subshell. In contrast, alkali metals, such as sodium and potassium, all have a single <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/> electron in their outermost subshell (an <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-c469fda205b238aa10a8206893999289_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"14\" style=\"vertical-align: 0px;\" \/><br \/>\n     configuration) and are members of Group 1 (Group I). These elements easily give up their extra electron and are thus highly reactive chemically. As you might expect, they also tend to form singly positive ions, such as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-339c65a3befb5d1b36e708f05166ba86_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#78;&#97;&#125;&#125;&#94;&#123;&#43;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"32\" style=\"vertical-align: 0px;\" \/>, by losing their loosely bound outermost electron. They are metals (conductors), because the loosely bound outer electron can move freely.<\/p>\n<p id=\"import-auto-id1431797\">Of course, other groups are also of interest. Carbon, silicon, and germanium, for example, have similar chemistries and are in Group 4 (Group IV). Carbon, in particular, is extraordinary in its ability to form many types of bonds and to be part of long chains, such as inorganic molecules. The large group of what are called transitional elements is characterized by the filling of the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4e8716946f6a868f015e0d62f28bc540_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#100;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"10\" style=\"vertical-align: 0px;\" \/> subshells and crossing of energy levels. Heavier groups, such as the lanthanide series, are more complex\u2014their shells do not fill in simple order. But the groups recognized by chemists such as Mendeleev have an explanation in the substructure of atoms.<\/p>\n<\/div>\n<div data-type=\"note\" class=\"note\" data-has-label=\"true\" data-label=\"\">\n<div data-type=\"title\" class=\"title\">PhET Explorations: Build an Atom<\/div>\n<p id=\"eip-id1815982\">Build an atom out of protons, neutrons, and electrons, and see how the element, charge, and mass change. Then play a game to test your ideas!<\/p>\n<div class=\"bc-figure figure\" id=\"eip-id1399668\">\n<div class=\"bc-figcaption figcaption\"><a href=\"\/resources\/5c21772c30c88ee989a6f25180e504fd3538c472\/build-an-atom_en.jar\">Build an Atom<\/a><\/div>\n<p><span data-type=\"media\" id=\"Phet_module_31.9\" data-alt=\"\"><a href=\"\/resources\/5c21772c30c88ee989a6f25180e504fd3538c472\/build-an-atom_en.jar\" data-type=\"image\"><img decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/clalonde\/wp-content\/uploads\/sites\/280\/2017\/10\/PhET_Icon.png\" data-media-type=\"image\/png\" alt=\"\" data-print=\"false\" width=\"450\" \/><\/a><span data-media-type=\"image\/png\" data-print=\"true\" data-src=\"\/resources\/075500ad9f71890a85fe3f7a4137ac08e2b7907c\/PhET_Icon.png\" data-type=\"image\"><\/span><\/span><\/p>\n<\/div>\n<\/div>\n<div class=\"section-summary\" data-depth=\"1\" id=\"fs-id2017186\">\n<h1 data-type=\"title\">Section Summary<\/h1>\n<ul id=\"fs-id1993103\">\n<li>The state of a system is completely described by a complete set of quantum numbers. This set is written as <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-2e083cc4a9b3dfc804602111fb65dd91_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#92;&#109;&#97;&#116;&#104;&#114;&#109;&#123;&#110;&#44;&#32;&#108;&#44;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#108;&#125;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#115;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"100\" style=\"vertical-align: -4px;\" \/>.<\/li>\n<li id=\"import-auto-id2396692\">The Pauli exclusion principle says that no two electrons can have the same set of quantum numbers; that is, no two electrons can be in the same state.<\/li>\n<li id=\"import-auto-id2409836\">This exclusion limits the number of electrons in atomic shells and subshells. Each value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b170995d512c659d8668b4e42e1fef6b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"11\" style=\"vertical-align: 0px;\" \/> corresponds to a shell, and each value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> corresponds to a subshell.<\/li>\n<li id=\"import-auto-id2953279\">The maximum number of electrons that can be in a subshell is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-963e5430880faa9445b64b5a5cea52b9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"70\" style=\"vertical-align: -4px;\" \/>.<\/li>\n<li id=\"import-auto-id3043936\">The maximum number of electrons that can be in a shell is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/>.<\/li>\n<\/ul>\n<\/div>\n<div class=\"conceptual-questions\" data-depth=\"1\" id=\"fs-id2991416\" data-element-type=\"conceptual-questions\">\n<h1 data-type=\"title\">Conceptual Questions<\/h1>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2929510\" data-element-type=\"conceptual-questions\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1557239\">\n<p id=\"import-auto-id2403115\">Identify the shell, subshell, and number of electrons for the following: (a) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e7ca8fad5fb1133f77e8f4707832864d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/>. (b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-0bf37a5ac342181909b9b1fd324f51bf_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#123;&#100;&#125;&#94;&#123;&#57;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"25\" style=\"vertical-align: -1px;\" \/>. (c) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-98374c605ed7eece1829acd5834dc4b5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"23\" style=\"vertical-align: 0px;\" \/>. (d) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-9e64f386b050c05139153111f1a12d71_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#53;&#123;&#103;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#54;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"32\" style=\"vertical-align: -4px;\" \/>.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" data-element-type=\"conceptual-questions\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1579144\">\n<p id=\"import-auto-id2978545\">Which of the following are not allowed? State which rule is violated for any that are not allowed. (a) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b36b7364f03971b2bbedf8472e0d75d5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#112;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"24\" style=\"vertical-align: -4px;\" \/> (b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-13fad76a72b911a0b629cfff219384b1_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#112;&#125;&#94;&#123;&#56;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/>(c) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-9a8d355f3aca57d823948d6290d2b3bf_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#103;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#49;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"31\" style=\"vertical-align: -4px;\" \/> (d) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-53faf2336898a96f13f369a5f6e39d50_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#123;&#102;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"26\" style=\"vertical-align: -4px;\" \/><\/p>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"problems-exercises\" data-depth=\"1\" id=\"fs-id1435351\" data-element-type=\"problems-exercises\">\n<h1 data-type=\"title\">Problem Exercises<\/h1>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3386479\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3386480\">\n<p id=\"import-auto-id2444624\">(a) How many electrons can be in the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3d48be04aadb63e5661f86d0948d7553_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#52;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"43\" style=\"vertical-align: -1px;\" \/> shell?<\/p>\n<p id=\"import-auto-id1598767\">(b) What are its subshells, and how many electrons can be in each?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3402641\">\n<p id=\"import-auto-id1598771\">(a) 32. (b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5aca0ac7498df1b703a3135d64db4b10_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#105;&#110;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#115;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#54;&#32;&#105;&#110;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#112;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#32;&#105;&#110;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#100;&#44;\" title=\"Rendered by QuickLaTeX.com\" height=\"17\" width=\"164\" style=\"vertical-align: -4px;\" \/> and 14 in <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-9c09a708375fde2676da319bcdfe8b24_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#102;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"10\" style=\"vertical-align: -4px;\" \/>, for a total of 32.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1616048\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1616049\">\n<p id=\"import-auto-id2435767\">(a) What is the minimum value of 1 for a subshell that has 11 electrons in it? <\/p>\n<p id=\"import-auto-id2435769\">(b) If this subshell is in the<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e5daa569ba25d5376c89af831dd5720c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#53;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: 0px;\" \/> shell, what is the spectroscopic notation for this atom?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1412034\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1412035\">\n<p id=\"import-auto-id3043928\">(a) If one subshell of an atom has 9 electrons in it, what is the minimum value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/>?  (b) What is the spectroscopic notation for this atom, if this subshell is part of the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/> shell?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id1539133\">\n<p id=\"import-auto-id1617226\">(a) 2<\/p>\n<p id=\"import-auto-id1617228\">(b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b89750f62a5eb75a411dbec218b9af5f_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#100;&#125;&#94;&#123;&#57;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"25\" style=\"vertical-align: 0px;\" \/><\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2683700\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2683701\">\n<p id=\"import-auto-id1599274\">(a) List all possible sets of quantum numbers <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e334b8700eb5e85cda0ca3221db793d6_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#108;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#108;&#125;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#115;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"108\" style=\"vertical-align: -4px;\" \/> for the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-85761a607075b960ff00638d721cfe9c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#51;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"43\" style=\"vertical-align: 0px;\" \/> shell, and determine the number of electrons that can be in the shell and each of its subshells.<\/p>\n<p id=\"import-auto-id3105697\">(b) Show that the number of electrons in the shell equals <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/> and that the number in each subshell is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-963e5430880faa9445b64b5a5cea52b9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"70\" style=\"vertical-align: -4px;\" \/>.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3355596\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3355597\">\n<p id=\"import-auto-id3026489\">Which of the following spectroscopic notations are not allowed? (a) <\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-763d209c6fd5f431b404a8e0ba7ccb2c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#53;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"23\" style=\"vertical-align: 0px;\" \/><\/p>\n<p>(b)<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e16794303db26ded0d65ffa838d92272_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#100;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"23\" style=\"vertical-align: -1px;\" \/><br \/>\n(c)<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a68d1eb6e7aff5a3ad8a3d8294123d55_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#123;&#115;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"24\" style=\"vertical-align: -1px;\" \/><br \/>\n(d)<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-157ce511c70381f61976816984c1b9c9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#55;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/><br \/>\n(e)<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-36bebf0358b3b70c7816748182b28623_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#53;&#123;&#103;&#125;&#94;&#123;&#49;&#53;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"32\" style=\"vertical-align: -4px;\" \/>. State which rule is violated for each that is not allowed.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id2668726\">\n<p id=\"import-auto-id3157292\">(b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-2dddef0c40545d81321d98cdab9fafc5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#92;&#103;&#101;&#32;&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"39\" style=\"vertical-align: -3px;\" \/>  is violated,<\/p>\n<p id=\"fs-id2373165\">(c) cannot have 3 electrons in <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ae1901659f469e6be883797bfd30f4f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"8\" width=\"8\" style=\"vertical-align: 0px;\" \/>  subshell since<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-bb124f328d112f9991b2e86af28a1311_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#62;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"123\" style=\"vertical-align: -4px;\" \/><\/p>\n<p id=\"fs-id2373168\">(d) cannot have 7 electrons in <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-3bf85f1087e9fbed3a319341134ac1a2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#112;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"10\" style=\"vertical-align: -4px;\" \/>  subshell since<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-c5b41d37a5e31efd2360bf5464f897aa_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#55;&#62;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#61;&#54;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"213\" style=\"vertical-align: -4px;\" \/><\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1480219\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1480220\">\n<p id=\"import-auto-id2602609\">Which of the following spectroscopic notations are allowed (that is, which violate none of the rules regarding values of quantum numbers)? (a) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7f95021541ee4b92dd6d70a3c9fe6aab_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#115;&#125;&#94;&#123;&#49;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"22\" style=\"vertical-align: -1px;\" \/>(b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-705f3dc95522336708a5fd93d99482b5_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#123;&#100;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"24\" style=\"vertical-align: -1px;\" \/>(c) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-f1c3a906930cb21599b0821bc4943c47_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#52;&#123;&#115;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"24\" style=\"vertical-align: -1px;\" \/> (d) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-157ce511c70381f61976816984c1b9c9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#123;&#112;&#125;&#94;&#123;&#55;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"25\" style=\"vertical-align: -4px;\" \/>(e) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-1a52519b546566fa82ac3b3f2f33aeae_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#54;&#123;&#104;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#50;&#48;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"33\" style=\"vertical-align: 0px;\" \/><\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1608615\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1608616\">\n<p id=\"import-auto-id1486422\">(a) Using the Pauli exclusion principle and the rules relating the allowed values of the quantum numbers <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-e334b8700eb5e85cda0ca3221db793d6_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#108;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#108;&#125;&#44;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#123;&#109;&#125;&#95;&#123;&#115;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"108\" style=\"vertical-align: -4px;\" \/>, prove that the maximum number of electrons in a subshell is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-59fb25810211a3ddc02a753b2998e579_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#123;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"15\" width=\"27\" style=\"vertical-align: 0px;\" \/>. <\/p>\n<p id=\"import-auto-id3210276\">(b) In a similar manner, prove that the maximum number of electrons in a shell is 2<em data-effect=\"italics\">n<\/em><sup>2<\/sup>.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id1443947\">\n<p id=\"import-auto-id1528331\">(a) The number of different values of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-76732a572f6c9fdce08b5d74dd7aced4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"20\" style=\"vertical-align: -3px;\" \/> is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-6643f65885f1126d7c5234e2bf8b0758_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&plusmn;&#108;&#44;&plusmn;&#92;&#108;&#101;&#102;&#116;&#40;&#108;&#45;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#44;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#46;&#46;&#44;&#125;&#48;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"106\" style=\"vertical-align: -4px;\" \/> for each <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-1ec0c2724a111d191779469643edd2ea_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#62;&#48;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"38\" style=\"vertical-align: 0px;\" \/> and one for <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-0af30abce842e897d4793d91ad1ea12d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;&#61;&#48;&#8658;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"107\" style=\"vertical-align: -4px;\" \/> Also an overall factor of 2 since each <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-76732a572f6c9fdce08b5d74dd7aced4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#108;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"20\" style=\"vertical-align: -3px;\" \/> can have <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-39d2d5cd720dde70463c6cd7244570a8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"22\" style=\"vertical-align: -3px;\" \/> equal to either <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-eda3ca21b30ce35ac8b10ebf3597bb3d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#43;&#49;&#47;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"40\" style=\"vertical-align: -5px;\" \/> or <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-1e408137e82c9fbd934e47a33b17620b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#45;&#49;&#47;&#50;&#8658;&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"109\" style=\"vertical-align: -5px;\" \/>. <\/p>\n<p id=\"import-auto-id1528334\">(b) for each value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/>, you get <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-963e5430880faa9445b64b5a5cea52b9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#108;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"70\" style=\"vertical-align: -4px;\" \/><\/p>\n<p id=\"import-auto-id1889894\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b02af48ed1b325ad3c9a9d6bb8ab3566_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#48;&#44;&#32;&#49;&#44;&#32;&#50;&#44;&#32;&#46;&#46;&#46;&#44;&#125;&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#92;&#116;&#101;&#120;&#116;&#123;&#45;&#49;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#8658;&#50;&#92;&#108;&#101;&#102;&#116;&#92;&#123;&#92;&#108;&#101;&#102;&#116;&#91;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#108;&#101;&#102;&#116;&#40;&#48;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#43;&#92;&#108;&#101;&#102;&#116;&#91;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#108;&#101;&#102;&#116;&#40;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#43;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#43;&#92;&#108;&#101;&#102;&#116;&#91;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#45;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#92;&#114;&#105;&#103;&#104;&#116;&#92;&#125;&#61;&#92;&#117;&#110;&#100;&#101;&#114;&#115;&#101;&#116;&#123;&#92;&#117;&#110;&#100;&#101;&#114;&#115;&#101;&#116;&#123;&#110;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#116;&#101;&#114;&#109;&#115;&#125;&#125;&#123;&#65080;&#125;&#125;&#123;&#50;&#92;&#108;&#101;&#102;&#116;&#91;&#49;&#43;&#51;&#43;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#43;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#110;&#45;&#51;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#110;&#45;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"60\" width=\"582\" style=\"vertical-align: -24px;\" \/> to see that the expression in the box is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-b7f2d099c8df5e6d321e9a5d931d5581_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#61;&#123;&#110;&#125;&#94;&#123;&#50;&#125;&#44;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"41\" style=\"vertical-align: -4px;\" \/> imagine taking <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-ce638acc15bac728cdcfa1e57206bef4_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#45;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"53\" style=\"vertical-align: -4px;\" \/> from the last term and adding it to first term <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5b32c340f7829f5e1be7a81ec83ee2ff_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#91;&#49;&#43;&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#92;&#116;&#101;&#120;&#116;&#123;&#45;&#49;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#51;&#43;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#43;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#110;&#45;&#51;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#110;&#45;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#45;&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#45;&#49;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#61;&#50;&#92;&#108;&#101;&#102;&#116;&#91;&#110;&#43;&#51;&#43;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#43;&#92;&#108;&#101;&#102;&#116;&#40;&#50;&#110;&#45;&#51;&#92;&#114;&#105;&#103;&#104;&#116;&#41;&#43;&#110;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"41\" width=\"582\" style=\"vertical-align: -5px;\" \/> Now take <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-729ea8999046cf95d90879895adc1a4f_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#108;&#101;&#102;&#116;&#40;&#110;&#45;&#51;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"53\" style=\"vertical-align: -4px;\" \/> from penultimate term and add to the second term <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-4a4d989162ccbb6b0bb7d85954f5091f_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#50;&#92;&#117;&#110;&#100;&#101;&#114;&#115;&#101;&#116;&#123;&#92;&#117;&#110;&#100;&#101;&#114;&#115;&#101;&#116;&#123;&#110;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#116;&#101;&#114;&#109;&#115;&#125;&#125;&#123;&#65080;&#125;&#125;&#123;&#92;&#108;&#101;&#102;&#116;&#91;&#110;&#43;&#110;&#43;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#43;&#110;&#43;&#110;&#92;&#114;&#105;&#103;&#104;&#116;&#93;&#125;&#61;&#123;&#50;&#110;&#125;&#94;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"39\" width=\"213\" style=\"vertical-align: -24px;\" \/>.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2313136\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2313137\">\n<p id=\"fs-id2313138\"><strong data-effect=\"bold\">Integrated Concepts<\/strong><\/p>\n<p id=\"fs-id2328449\">Estimate the density of a nucleus by calculating the density of a proton, taking it to be a sphere 1.2 fm in diameter. Compare your result with the value estimated in this chapter.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2378469\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2378470\">\n<p id=\"import-auto-id2444200\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2588858\">The electric and magnetic forces on an electron in the CRT in <a href=\"\/contents\/7ecc38ba-f855-43c4-bad7-50c40b70556d@6#fs-id961353\" class=\"autogenerated-content\">(Figure)<\/a> are supposed to be in opposite directions. Verify this by determining the direction of each force for the situation shown. Explain how you obtain the directions (that is, identify the rules used).<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3099218\">\n<p id=\"import-auto-id3063565\">The electric force on the electron is up (toward the positively charged plate). The magnetic force is down (by the RHR).<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3099228\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3099229\">\n<p id=\"import-auto-id1474941\">(a) What is the distance between the slits of a diffraction grating that produces a first-order maximum for the first Balmer line at an angle of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-c918e80bba36ea1d2e565858d4a55186_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#50;&#48;&#46;&#48;&ordm;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"32\" style=\"vertical-align: 0px;\" \/>?<\/p>\n<p id=\"fs-id1590957\">(b) At what angle will the fourth line of the Balmer series appear in first order?<\/p>\n<p id=\"fs-id2305542\">(c) At what angle will the second-order maximum be for the first line?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id2378650\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id2378651\">\n<p id=\"import-auto-id2929690\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id1464238\">A galaxy moving away from the earth has a speed of<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-f9bd738168225365b2b300e890256031_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#48;&#46;&#48;&#49;&#48;&#48;&#125;&#99;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"57\" style=\"vertical-align: -1px;\" \/>. What wavelength do we observe for an <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-88e7e8c9b41feb7de1510d6d02a0f0fa_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#105;&#125;&#125;&#61;&#55;\" title=\"Rendered by QuickLaTeX.com\" height=\"17\" width=\"48\" style=\"vertical-align: -4px;\" \/> to <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-f598cc02b34fff29f8de870f758436bf_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#102;&#125;&#125;&#61;&#50;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"47\" style=\"vertical-align: -4px;\" \/> transition for hydrogen in that galaxy?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3187298\">\n<p id=\"import-auto-id3035430\">401 nm<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3187307\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3187308\">\n<p id=\"import-auto-id2929099\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id1986345\">Calculate the velocity of a star moving relative to the earth if you observe a wavelength of 91.0 nm for ionized hydrogen capturing an electron directly into the lowest orbital (that is, a <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-24562c736fa20a0ed22801e3f71e5184_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#105;&#125;&#125;&#61;&#92;&#105;&#110;&#102;&#116;&#121;&#32;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"56\" style=\"vertical-align: -4px;\" \/> to <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-43da531ce014545cc0f87de6cd2a4a2e_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#102;&#125;&#125;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"47\" style=\"vertical-align: -4px;\" \/>, or a Lyman series transition).<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3188615\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3188616\">\n<p id=\"import-auto-id2397270\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3090531\">In a Millikan oil-drop experiment using a setup like that in <a href=\"\/contents\/7ecc38ba-f855-43c4-bad7-50c40b70556d@6#fs-id2010482\" class=\"autogenerated-content\">(Figure)<\/a>, a 500-V potential difference is applied to plates separated by 2.50 cm. (a) What is the mass of an oil drop having two extra electrons that is suspended motionless by the field between the plates? (b) What is the diameter of the drop, assuming it is a sphere with the density of olive oil?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id2919072\">\n<p id=\"import-auto-id3357873\">(a) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-2327852e4aa06294d60edb62e28f4eae_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#54;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#53;&#52;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#45;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#54;&#125;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#107;&#103;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"97\" style=\"vertical-align: -3px;\" \/><\/p>\n<p id=\"import-auto-id3025603\">(b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-1cf0c126aa933fbf12761730e61cb2c9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#53;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#53;&#52;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#45;&#55;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#109;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"87\" style=\"vertical-align: -1px;\" \/><\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1539051\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1539052\">\n<p id=\"import-auto-id3253406\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3148820\">What double-slit separation would produce a first-order maximum at <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-96d83cc0cebbb8fb136fedaed7ef93fe_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#51;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#48;&#48;&ordm;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"32\" style=\"vertical-align: 0px;\" \/> for 25.0-keV x rays? The small answer indicates that the wave character of x rays is best determined by having them interact with very small objects such as atoms and molecules.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3450401\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3450402\">\n<p id=\"import-auto-id2400659\"><strong>Integrated Concepts <\/strong><\/p>\n<p id=\"eip-id1616692\">In a laboratory experiment designed to duplicate Thomson\u2019s determination of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5136d518f7a9b228e296e43ef1f5ae31_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#113;&#125;&#95;&#123;&#101;&#125;&#47;&#123;&#109;&#125;&#95;&#123;&#101;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"46\" style=\"vertical-align: -5px;\" \/>, a beam of electrons having a velocity of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-0d05d842956184012ed263189649296d_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#54;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#48;&#48;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#55;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#109;&#47;&#115;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"92\" style=\"vertical-align: -4px;\" \/> enters a <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a214475aef498be4f991719638e3865b_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#53;&#46;&#48;&#48;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#45;&#51;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#84;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"85\" style=\"vertical-align: -1px;\" \/> magnetic field. The beam moves perpendicular to the field in a path having a 6.80-cm radius of curvature. Determine <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-5136d518f7a9b228e296e43ef1f5ae31_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#113;&#125;&#95;&#123;&#101;&#125;&#47;&#123;&#109;&#125;&#95;&#123;&#101;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"46\" style=\"vertical-align: -5px;\" \/> from these observations, and compare the result with the known value.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id2519902\">\n<p id=\"import-auto-id3163259\"><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-9977c00368dbabcc024871c65ffc071c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#55;&#54;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#49;&#125;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#67;&#47;&#107;&#103;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"107\" style=\"vertical-align: -4px;\" \/><br \/>\n    , which agrees with the known value of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-8f3993e19939ec46c62069b9c01b48f8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#55;&#53;&#57;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#49;&#125;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#67;&#47;&#107;&#103;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"116\" style=\"vertical-align: -4px;\" \/> to within the precision of the measurement\n    <\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1467272\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1467273\">\n<p id=\"fs-id1467274\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"fs-id1437945\">Find the value of  <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/>, the orbital angular momentum quantum number, for the moon around the earth. The extremely large value obtained implies that it is impossible to tell the difference between adjacent quantized orbits for macroscopic objects.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3065607\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3065608\">\n<p><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2424158\">Particles called muons exist in cosmic rays and can be created in particle accelerators. Muons are very similar to electrons, having the same charge and spin, but they have a mass 207 times greater. When muons are captured by an atom, they orbit just like an electron but with a smaller radius, since the mass in <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7a1a8fd815a8954087b53d1db44e12fb_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#97;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#66;&#125;&#125;&#61;&#92;&#102;&#114;&#97;&#99;&#123;&#123;&#104;&#125;&#94;&#123;&#50;&#125;&#125;&#123;&#123;&#52;&#92;&#112;&#105;&#32;&#125;&#94;&#123;&#50;&#125;&#123;&#109;&#125;&#95;&#123;&#101;&#125;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#107;&#113;&#125;&#125;&#95;&#123;&#101;&#125;&#94;&#123;&#50;&#125;&#125;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#48;&#46;&#53;&#50;&#57;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#45;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#109;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"29\" width=\"236\" style=\"vertical-align: -11px;\" \/> is 207 <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a9d94bf65193c4d7c685b6c3c4012aa9_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#109;&#125;&#95;&#123;&#101;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"11\" width=\"22\" style=\"vertical-align: -3px;\" \/>.<\/p>\n<p id=\"import-auto-id3305689\">(a) Calculate the radius of the <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-a51661019cc26a5931f8cb0d5fd63f30_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#110;&#61;&#49;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"42\" style=\"vertical-align: -1px;\" \/> orbit for a muon in a uranium ion (<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-bb51dda6ed4f921d8e7e5225e2cd2dae_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#90;&#61;&#92;&#116;&#101;&#120;&#116;&#123;&#57;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"53\" style=\"vertical-align: 0px;\" \/>).<\/p>\n<p id=\"import-auto-id3176618\">(b) Compare this with the 7.5-fm radius of a uranium nucleus. Note that since the muon orbits inside the electron, it falls into a hydrogen-like orbit. Since your answer is less than the radius of the nucleus, you can see that the photons emitted as the muon falls into its lowest orbit can give information about the nucleus.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3452608\">\n<p id=\"import-auto-id3063530\">(a) 2.78 fm<\/p>\n<p id=\"import-auto-id3063532\">(b) 0.37 of the nuclear radius.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3568692\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3568693\">\n<p id=\"fs-id3568694\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"fs-id3568697\">Calculate the minimum amount of energy in joules needed to create a population inversion in a helium-neon laser containing <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-776e5f6d1431b7f46bf057cbe160c3fc_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#48;&#48;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#45;&#52;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"66\" style=\"vertical-align: -1px;\" \/><br \/>\n     moles of neon.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3168724\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3168725\">\n<p id=\"import-auto-id3112318\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3305248\">A carbon dioxide laser used in surgery emits infrared radiation with a wavelength of<br \/>\n<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-39348a563007d43f3b70d2cebd66f25c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#46;&#54;&#32;&mu;&#109;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"51\" style=\"vertical-align: -1px;\" \/>. In 1.00 ms, this laser raised the temperature of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-def4f0a5605e671fa37a849b068980a3_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#46;&#48;&#48;&#32;&#99;&#109;&#125;&#125;&#94;&#123;&#51;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"66\" style=\"vertical-align: -1px;\" \/> of flesh to <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-43ef7061faa1f975bd075822e41173db_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#48;&ordm;&#67;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"38\" style=\"vertical-align: -1px;\" \/> and evaporated it. <\/p>\n<p id=\"import-auto-id3091780\">(a) How many photons were required? You may assume flesh has the same heat of vaporization as water. (b) What was the minimum power output during the flash?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3066149\">\n<p id=\"import-auto-id2930592\">(a) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-1fa11991221627ce397ddf0317a7247c_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#51;&#52;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#50;&#51;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"62\" style=\"vertical-align: -1px;\" \/><\/p>\n<p id=\"import-auto-id3035465\">(b) 2.52 MW<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1545858\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1545859\">\n<p id=\"import-auto-id3035473\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2448326\"> Suppose an MRI scanner uses 100-MHz radio waves.<\/p>\n<p id=\"import-auto-id2627186\">(a) Calculate the photon energy.<\/p>\n<p id=\"import-auto-id2627188\">(b) How does this compare to typical molecular binding energies?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1545878\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1545879\">\n<p id=\"import-auto-id2627194\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2209138\"> (a) An excimer laser used for vision correction emits 193-nm UV. Calculate the photon energy in eV.<\/p>\n<p id=\"import-auto-id2627225\">(b) These photons are used to evaporate corneal tissue, which is very similar to water in its properties. Calculate the amount of energy needed per molecule of water to make the phase change from liquid to gas. That is, divide the heat of vaporization in kJ\/kg by the number of water molecules in a kilogram.<\/p>\n<p id=\"import-auto-id2627230\">(c) Convert this to eV and compare to the photon energy. Discuss the implications.<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id1545901\">\n<p id=\"import-auto-id2627234\">(a) 6.42 eV<\/p>\n<p id=\"import-auto-id2627236\">(b) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-d12e0290878ff061fecfbe9d9aa71424_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#55;&#46;&#50;&#55;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#45;&#92;&#116;&#101;&#120;&#116;&#123;&#50;&#48;&#125;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#74;&#47;&#109;&#111;&#108;&#101;&#99;&#117;&#108;&#101;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"19\" width=\"165\" style=\"vertical-align: -4px;\" \/><\/p>\n<p id=\"import-auto-id1539108\">(c) 0.454 eV, 14.1 times less than a single UV photon. Therefore, each photon will evaporate approximately 14 molecules of tissue. This gives the surgeon a rather precise method of removing corneal tissue from the surface of the eye.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1985063\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1985064\">\n<p id=\"import-auto-id3417962\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3036655\"> A neighboring galaxy rotates on its axis so that stars on one side move toward us as fast as 200 km\/s, while those on the other side move away as fast as 200 km\/s. This causes the EM radiation we receive to be Doppler shifted by velocities over the entire range of \u00b1200 km\/s. What range of wavelengths will we observe for the 656.0-nm line in the Balmer series of hydrogen emitted by stars in this galaxy. (This is called line broadening.)<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id1985082\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id1985083\">\n<p id=\"import-auto-id2662784\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id2519593\">A pulsar is a rapidly spinning remnant of a supernova. It rotates on its axis, sweeping hydrogen along with it so that hydrogen on one side moves toward us as fast as 50.0 km\/s, while that on the other side moves away as fast as 50.0 km\/s. This means that the EM radiation we receive will be Doppler shifted over a range of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-47bc98ec44a44b6f5f39ddb7f5e0269e_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&plusmn;&#92;&#116;&#101;&#120;&#116;&#123;&#53;&#48;&#125;&#46;&#48;&#32;&#107;&#109;&#47;&#115;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"74\" style=\"vertical-align: -5px;\" \/>. What range of wavelengths will we observe for the 91.20-nm line in the Lyman series of hydrogen? (Such line broadening is observed and actually provides part of the evidence for rapid rotation.)<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3303403\">\n<p id=\"import-auto-id3117059\">91.18 nm to 91.22 nm<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3303412\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3303413\">\n<p id=\"import-auto-id3117068\"><strong>Integrated Concepts<\/strong><\/p>\n<p id=\"eip-id3080551\"> Prove that the velocity of charged particles moving along a straight path through perpendicular electric and magnetic fields is <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-7d2436972f98a26125de0e3bde2dfa28_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#118;&#61;&#69;&#47;&#66;\" title=\"Rendered by QuickLaTeX.com\" height=\"18\" width=\"70\" style=\"vertical-align: -5px;\" \/>. Thus crossed electric and magnetic fields can be used as a velocity selector independent of the charge and mass of the particle involved.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3303454\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3303455\">\n<p id=\"import-auto-id3105945\"><strong>Unreasonable Results<\/strong><\/p>\n<p id=\"eip-id2570741\">(a) What voltage must be applied to an X-ray tube to obtain 0.0100-fm-wavelength X-rays for use in exploring the details of nuclei? (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?<\/p>\n<\/div>\n<div data-type=\"solution\" class=\"solution\" id=\"fs-id3303467\">\n<p id=\"import-auto-id3105953\">(a) <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-baba1830fe477a742160a868da9d50bb_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#49;&#92;&#116;&#101;&#120;&#116;&#123;&#46;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#50;&#52;&#125;&times;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#48;&#125;&#125;&#94;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#49;&#49;&#125;&#125;&#92;&#112;&#104;&#97;&#110;&#116;&#111;&#109;&#123;&#92;&#114;&#117;&#108;&#101;&#123;&#48;&#46;&#50;&#53;&#101;&#109;&#125;&#123;&#48;&#101;&#120;&#125;&#125;&#92;&#116;&#101;&#120;&#116;&#123;&#86;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"16\" width=\"80\" style=\"vertical-align: -1px;\" \/><\/p>\n<p id=\"import-auto-id1526234\">(b) The voltage is extremely large compared with any practical value.<\/p>\n<p id=\"import-auto-id2625305\">(c) The assumption of such a short wavelength by this method is unreasonable.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3043155\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3043156\">\n<p id=\"import-auto-id2625313\"><strong>Unreasonable Results<\/strong><\/p>\n<p id=\"eip-id3091254\">A student in a physics laboratory observes a hydrogen spectrum with a diffraction grating for the purpose of measuring the wavelengths of the emitted radiation. In the spectrum, she observes a yellow line and finds its wavelength to be 589 nm. (a) Assuming this is part of the Balmer series, determine <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-273f3f9d49017beaed13af3eff733195_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#105;&#125;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"15\" style=\"vertical-align: -4px;\" \/>, the principal quantum number of the initial state. (b) What is unreasonable about this result? (c) Which assumptions are unreasonable or inconsistent?<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3016578\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3016579\">\n<p id=\"import-auto-id3201432\"><strong>Construct Your Own Problem<\/strong><\/p>\n<p id=\"eip-id3080544\"> The solar corona is so hot that most atoms in it are ionized. Consider a hydrogen-like atom in the corona that has only a single electron. Construct a problem in which you calculate selected spectral energies and wavelengths of the Lyman, Balmer, or other series of this atom that could be used to identify its presence in a very hot gas. You will need to choose the atomic number of the atom, identify the element, and choose which spectral lines to consider.<\/p>\n<\/div>\n<\/div>\n<div data-type=\"exercise\" class=\"exercise\" id=\"fs-id3016593\" data-element-type=\"problems-exercises\">\n<div data-type=\"problem\" class=\"problem\" id=\"fs-id3016594\">\n<p id=\"import-auto-id3192240\"><strong>Construct Your Own Problem<\/strong><\/p>\n<p id=\"eip-id3188190\">Consider the Doppler-shifted hydrogen spectrum received from a rapidly receding galaxy. Construct a problem in which you calculate the energies of selected spectral lines in the Balmer series and examine whether they can be described with a formula like that in the equation <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-d46e8dbbfcf8225573554ef28220344a_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#92;&#102;&#114;&#97;&#99;&#123;&#49;&#125;&#123;&#92;&#108;&#97;&#109;&#98;&#100;&#97;&#32;&#125;&#61;&#82;&#92;&#108;&#101;&#102;&#116;&#40;&#92;&#102;&#114;&#97;&#99;&#123;&#49;&#125;&#123;&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#102;&#125;&#125;&#94;&#123;&#50;&#125;&#125;&#45;&#92;&#102;&#114;&#97;&#99;&#123;&#49;&#125;&#123;&#123;&#110;&#125;&#95;&#123;&#92;&#116;&#101;&#120;&#116;&#123;&#105;&#125;&#125;&#94;&#123;&#50;&#125;&#125;&#92;&#114;&#105;&#103;&#104;&#116;&#41;\" title=\"Rendered by QuickLaTeX.com\" height=\"34\" width=\"128\" style=\"vertical-align: -13px;\" \/>, but with a different constant <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-dae6bae3dcdac4629730754352c5e329_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#82;\" title=\"Rendered by QuickLaTeX.com\" height=\"12\" width=\"14\" style=\"vertical-align: 0px;\" \/>.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<div data-type=\"footnote-refs\">\n<h2 data-type=\"footnote-title\">Footnotes<\/h2>\n<ol>\n<li><a data-type=\"footnote-ref\" href=\"#footnote-ref1\">1<\/a> It is unusual to deal with subshells having <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> greater than 6, but when encountered, they continue to be labeled in alphabetical order.<\/li>\n<\/ol>\n<\/div>\n<div data-type=\"glossary\" class=\"textbox shaded\">\n<h2 data-type=\"glossary-title\">Glossary<\/h2>\n<dl class=\"definition\" id=\"import-auto-id3081439\">\n<dt>atomic number<\/dt>\n<dd id=\"fs-id2520893\">the number of protons in the nucleus of an atom<\/dd>\n<\/dl>\n<dl class=\"definition\" id=\"import-auto-id3081441\">\n<dt>Pauli exclusion principle<\/dt>\n<dd id=\"fs-id2520902\">a principle that states that no two electrons can have the same set of quantum numbers; that is, no two electrons can be in the same state<\/dd>\n<\/dl>\n<dl class=\"definition\" id=\"import-auto-id3081445\">\n<dt>shell<\/dt>\n<dd id=\"fs-id3066054\">a probability cloud for electrons that has a single principal quantum number<\/dd>\n<\/dl>\n<dl class=\"definition\" id=\"import-auto-id3081447\">\n<dt>subshell<\/dt>\n<dd id=\"fs-id3066064\">the probability cloud for electrons that has a single angular momentum quantum number <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-content\/ql-cache\/quicklatex.com-502276c66966e5a861539c7de60c26c0_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#108;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"5\" style=\"vertical-align: 0px;\" \/> <\/dd>\n<\/dl>\n<\/div>\n","protected":false},"author":211,"menu_order":1,"template":"","meta":{"pb_show_title":"on","pb_short_title":"","pb_subtitle":"","pb_authors":[],"pb_section_license":"all-rights-reserved"},"chapter-type":[],"contributor":[],"license":[56],"class_list":["post-1661","chapter","type-chapter","status-publish","hentry","license-all-rights-reserved"],"part":1582,"_links":{"self":[{"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/chapters\/1661","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/chapters"}],"about":[{"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/wp\/v2\/types\/chapter"}],"author":[{"embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/wp\/v2\/users\/211"}],"version-history":[{"count":1,"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/chapters\/1661\/revisions"}],"predecessor-version":[{"id":1662,"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/chapters\/1661\/revisions\/1662"}],"part":[{"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/parts\/1582"}],"metadata":[{"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/chapters\/1661\/metadata\/"}],"wp:attachment":[{"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/wp\/v2\/media?parent=1661"}],"wp:term":[{"taxonomy":"chapter-type","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/pressbooks\/v2\/chapter-type?post=1661"},{"taxonomy":"contributor","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/wp\/v2\/contributor?post=1661"},{"taxonomy":"license","embeddable":true,"href":"https:\/\/pressbooks.bccampus.ca\/ubcbatessandbox\/wp-json\/wp\/v2\/license?post=1661"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}