Ionic bonds

Reactive atoms that are close to filling their valence shells will pull on the valence electrons of nearby atoms with force. This property is called electronegativity. The closer an atom is to filling its valence shell, the more electronegative that atom is. For example, chlorine (Cl) has an atomic number of 17. The valence shell of Cl contains seven out of a total possible eight electrons. Cl requires only one electron to fill its valence shell and it is very electronegative compared to sodium (Na), for example. Na has an atomic number of 11 and its valence shell contains one out of a possible eight electrons. Therefore, Cl will pull on the single valence electron of Na with force. Na will transfer its valence electron to Cl, resulting in two ions: Na+ because Na has transferred a valence electron to Cl and Cl because it has gained an electron. The two oppositely charged ions are attracted to one another. The resulting electrostatic attraction between Na+ and Cl is called an ionic bond and the resulting compound is sodium chloride (NaCl).

 

IMPORTANT: the transfer of an electron from Na to Cl is NOT the bond. The ionic bond is the electrostatic attraction between the resulting ions.

 

Activity: Select the correct electron from Na and drag it to the appropriate location to complete the electron transfer with Cl, forming two ions and an ionic bond.
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Chemistry for Biology 1190 Students Copyright © by Julia Wong is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License, except where otherwise noted.

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